3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Base Information

Chemical Name:3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester
CAS No.:153790-79-5
Molecular Formula:C₃₃H₄₄O₆Si₂
Molecular Weight:592.88
Hs Code.:

Synonyms:3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Suppliers and Price of 3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

There total 4 articles about 3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 153790-78-4
4-(tert-Butyl-diphenyl-silanyloxy)-2-hydroxy-3,5,6-trimethyl-benzoic acid 2-trimethylsilanyl-ethyl ester

: 153790-79-5
3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: In acetic acid; at 25 ℃; for 5h;

Reference yield:

: 148238-89-5
ethyl 3-formyl-4,6-dihydroxy-2,5-dimethylbenzoate

: 153790-79-5
3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 91 percent / Zn; HgCl₂; aq. HCl / ethanol / Heating

2.1: NaH / benzene / 25 °C

2.2: 63 percent / benzene / 4 h / 120 °C

3.1: 91 percent / triethylamine; DMAP / CH₂Cl₂ / 96 h / 25 °C

4.1: 57 percent / AcOH / 5 h / 25 °C

With hydrogenchloride; dmap; sodium hydride; acetic acid; triethylamine; mercury dichloride; zinc; In ethanol; dichloromethane; benzene; 1.1: Clemensen reduction;
DOI:10.1021/ja0112341

Reference yield:

: 153790-77-3
2,4-Dihydroxy-3,5,6-trimethyl-benzoic acid 2-trimethylsilanyl-ethyl ester

: 153790-79-5
3-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-2,3,5-trimethyl-6-oxo-cyclohexa-1,4-dienecarboxylic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / triethylamine; DMAP / CH₂Cl₂ / 96 h / 25 °C

2: 57 percent / AcOH / 5 h / 25 °C

With dmap; acetic acid; triethylamine; In dichloromethane;
DOI:10.1021/ja0112341