2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane

Base Information

• Chemical Name: 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane
• CAS No.: 23516-76-9
• Molecular Formula: C₁₈H₂₂N₂O₄S₄
• Molecular Weight: 458.648
• Mol file: 23516-76-9.mol

Synonyms:2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane

Chemical Property of 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane

There total 5 articles about 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

C18H23NO3S2 → 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane (23516-76-9) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 1.3h; Inert atmosphere;

DOI:10.1039/c6cc01068g

Reference yield: 58.0%

C15H17NO4S3 → 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane (23516-76-9)

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.75h; Inert atmosphere;

DOI:10.1002/adsc.202100424

Reference yield:

chloroamine-T (127-65-1) → 2,6-bis-(toluene-4-sulfonyl)-[1,5,2,6]dithiadiazocane (23516-76-9)

Guidance literature:

Multi-step reaction with 3 steps

1: methanol / 16 h

2: toluene / 3.5 h / 80 °C

3: sodium hydride / mineral oil; tetrahydrofuran; Petroleum ether / 2.5 h / Cooling with ice

With sodium hydride; In tetrahydrofuran; methanol; toluene; mineral oil; Petroleum ether;

DOI:10.1039/c6cc01068g

upstream raw materials:

chloroamine-T

S-(2-Chlorethyl)-N-tosylsulfenamid