Technology Process of cyclohex-2-en-1-yl-1-d methyl carbonate
There total 1 articles about cyclohex-2-en-1-yl-1-d methyl carbonate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: sodium borodeuteride; cerium(III) chloride heptahydrate; methanol / 1 h / 0 °C
2: pyridine / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere
With
pyridine; methanol; sodium borodeuteride; cerium(III) chloride heptahydrate;
In
dichloromethane;
DOI:10.1021/jacs.0c08899
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; C24H44N2P2Si2; potassium tert-butylate / tetrahydrofuran / 0.25 h / Inert atmosphere; Glovebox; Sealed tube
1.2: 24 h / 50 °C / Inert atmosphere; Sealed tube
2.1: toluene / 19 h / 60 °C / Inert atmosphere
With
tetrakis(acetonitrile)copper(I)tetrafluoroborate; potassium tert-butylate; C24H44N2P2Si2;
In
tetrahydrofuran; toluene;
DOI:10.1021/jacs.0c08899
- Guidance literature:
-
bis(pinacol)diborane;
With
tetrakis(acetonitrile)copper(I)tetrafluoroborate; potassium tert-butylate; C24H44N2P2Si2;
In
tetrahydrofuran;
for 0.25h;
Inert atmosphere;
Glovebox;
Sealed tube;
cyclohex-2-en-1-yl-1-d methyl carbonate;
In
tetrahydrofuran;
at 50 ℃;
for 24h;
Reagent/catalyst;
enantioselective reaction;
Catalytic behavior;
Inert atmosphere;
Sealed tube;
DOI:10.1021/jacs.0c08899
