4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene

Base Information

• Chemical Name: 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene
• CAS No.: 1260156-77-1
• Molecular Formula: C₃₂H₂₉BrO₂
• Molecular Weight: 525.485
• Mol file: 1260156-77-1.mol

Synonyms:4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene

Chemical Property of 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene

There total 1 articles about 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

4,5-bis-(2,4,6-trimethylphenoxy)anthracen-9(10H)-one (1225202-01-6) → 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene (1260156-77-1)

Guidance literature:

With phosphorus tribromide; at 110 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ja109671f

Reference yield: 89.0%

Trimethyl borate (121-43-7,63156-11-6) + 4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene (1260156-77-1) → [4,5-bis(2,4,6-trimethylphenoxy)-9-anthryl]dimethoxyborane (1376607-94-1)

Guidance literature:

4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ja3036042

Reference yield: 63.0%

4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene (1260156-77-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene (1343490-18-5)

Guidance literature:

4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol202493c

upstream raw materials:

4,5-bis-(2,4,6-trimethylphenoxy)anthracen-9(10H)-one

Downstream raw materials:

1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene

C₃₀H₁₁BS₂(OC₆H₂(CH₃)3)2

[4,5-bis(2,4,6-trimethylphenoxy)-9-anthryl]dimethoxyborane

6,13-bis(4,5-dimesityloxyanthr-9-yl)-6,13-dihydro-6,13-diborapentacene