Technology Process of 1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene
There total 1 articles about 1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
4,5-bis(2,4,6-trimethylphenoxy)-9-bromoanthracene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 2h;
Inert atmosphere;
N,N-dimethyl-formamide;
In
tetrahydrofuran; hexane;
at -78 - 20 ℃;
Inert atmosphere;
DOI:10.1021/ol202493c
- Guidance literature:
-
2-ethyl-1H-pyrrole; 1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene;
With
trifluoroacetic acid;
at 20 ℃;
for 3h;
Inert atmosphere;
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
at 20 ℃;
for 0.666667h;
Inert atmosphere;
With
boron trifluoride diethyl etherate; triethylamine;
at 20 ℃;
for 1h;
Inert atmosphere;
DOI:10.1021/ol202493c
- Guidance literature:
-
1,8-bis(2,4,6-trimethylphenoxy)-10-formylanthracene; 5,10-bis(pentafluorophenyl)tripyrrane;
With
methanesulfonic acid;
In
dichloromethane;
at 0 ℃;
for 2h;
Inert atmosphere;
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
at 20 ℃;
for 1h;
Inert atmosphere;
DOI:10.1002/anie.201204446
