bis(benzonitrile)phthalocyaninate ruthenium(II)

Base Information

• Chemical Name: bis(benzonitrile)phthalocyaninate ruthenium(II)
• CAS No.: 150814-59-8
• Molecular Formula: C₄₆H₂₆N₁₀Ru
• Molecular Weight: 819.849
• Mol file: 150814-59-8.mol

Synonyms:bis(benzonitrile)phthalocyaninate ruthenium(II)

Chemical Property of bis(benzonitrile)phthalocyaninate ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(benzonitrile)phthalocyaninate ruthenium(II)

There total 3 articles about bis(benzonitrile)phthalocyaninate ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

bis-ammine phthalocyaninatoruthenium(II) (150814-60-1) + benzonitrile (100-47-0) → bis(benzonitrile)phthalocyaninate ruthenium(II) (150814-59-8)

Guidance literature:

In chloroform; benzonitrile; components refluxing under N2 in dar in pure benzonitrile for 24 h, the for 1 h in C6H5CN/CHCl3 3:2, pptn. on MeOH addn. in dark; ppt. rinsing with EtOH, drying;

DOI:10.1021/jp992438v

Reference yield: 40.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 29H,31H-Phthalocyanine (574-93-6) + benzonitrile (100-47-0) → bis(benzonitrile)phthalocyaninate ruthenium(II) (150814-59-8)

Guidance literature:

for 24h; Sealed tube; Reflux;

DOI:10.1039/c7tb00958e

Reference yield: 34.0%

isoindole-1,3-diylidenediamine (160956-25-2,160956-26-3,160956-27-4,160956-28-5,160956-29-6) + benzonitrile (100-47-0) → bis(benzonitrile)phthalocyaninate ruthenium(II) (150814-59-8)

Guidance literature:

isoindole-1,3-diylidenediamine; With ruthenium(III) chloride trihydrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In 2-ethoxy-ethanol; at 140 ℃; for 18h; Inert atmosphere;

benzonitrile; at 100 ℃; for 5h; Inert atmosphere;

DOI:10.1039/c0cp01015d

upstream raw materials:

bis-ammine phthalocyaninatoruthenium(II)

benzonitrile

isoindole-1,3-diylidenediamine

dodecacarbonyl-triangulo-triruthenium

Downstream raw materials:

C₁₃₀H₁₆₂N₁₀O₄₀Ru