5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride

Base Information

• Chemical Name: 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride
• CAS No.: 935510-24-0
• Molecular Formula: C₅₂H₂₈ClMnN₄
• Molecular Weight: 799.212
• Mol file: 935510-24-0.mol

Synonyms:5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride

Chemical Property of 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride

There total 3 articles about 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

5,10,15,20-tetra(4-ethynylphenyl)porphyrin (160240-15-3) → 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride (935510-24-0)

Guidance literature:

With manganese(ll) chloride; In N,N-dimethyl-formamide; for 72h; Heating / reflux;

Reference yield: 44.0%

meso-tetrakis<4-<2-(trimethylsilyl)ethynyl>phenyl>porphyrin → 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride (935510-24-0)

Guidance literature:

meso-tetrakis<4-<2-(trimethylsilyl)ethynyl>phenyl>porphyrin; With manganese (II) acetate tetrahydrate; In N,N-dimethyl-formamide; Inert atmosphere; Reflux;

With sodium chloride; In dichloromethane; water; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2009.02.020

Reference yield: 44.0%

5,10,15,20-tetrakis-(4-[(trimethylsilyl)ethynyl]phenyl)porphyrin + manganese (II) acetate tetrahydrate (6156-78-1) + sodium chloride (7647-14-5) → 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinmanganese(III) chloride (935510-24-0)

Guidance literature:

In dichloromethane; water; N,N-dimethyl-formamide; (N2); Schlenk technique; Mn salt was added to soln. of porphyrin in DMF;stirred under reflux overnight; cooled to room temp.; ice-cooled soln. of Na Cl was added; filtered; dissolved in CH2Cl2; satd. soln. of NaCl w as added; stirred (room temp., 3 h); org. layer septd.; dried (MgSO4); concd. (vac.); chromd. (alumina, 5% MeOH/CHCl3); evapd. (vac.);

DOI:10.1016/j.jorganchem.2009.02.020

upstream raw materials:

5,10,15,20-tetra(4-ethynylphenyl)porphyrin

manganese (II) acetate tetrahydrate

sodium chloride

Downstream raw materials:

5,10,15,20-tetrakis-(1-hexyl-4-phenyl-1,2,3-triazolo)porphyrinmanganese(III) chloride

C₁₀₀H₁₂₈ClMnN₁₆