Technology Process of C25H42O3Si2
There total 4 articles about C25H42O3Si2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C18H22O3; (trimethylsilyl)methylmagnesium chloride;
With
copper(l) iodide;
In
tetrahydrofuran; diethyl ether;
at -50 - -30 ℃;
for 0.5h;
Inert atmosphere;
chloro-trimethyl-silane;
With
N,N,N,N,N,N-hexamethylphosphoric triamide; triethylamine;
In
tetrahydrofuran; diethyl ether;
at -78 - 24 ℃;
for 1.33333h;
Inert atmosphere;
DOI:10.1021/ja200034b
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: pyridinium p-toluenesulfonate / acetonitrile / 1.75 h / 24 - 50 °C / Inert atmosphere
1.2: 24 °C / Inert atmosphere
2.1: copper(l) iodide / tetrahydrofuran; diethyl ether / 0.5 h / -50 - -30 °C / Inert atmosphere
2.2: 1.33 h / -78 - 24 °C / Inert atmosphere
With
copper(l) iodide; pyridinium p-toluenesulfonate;
In
tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1021/ja200034b
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: oxygen; palladium diacetate / dimethyl sulfoxide / 31 h / 24 °C
2.1: pyridinium p-toluenesulfonate / acetonitrile / 1.75 h / 24 - 50 °C / Inert atmosphere
2.2: 24 °C / Inert atmosphere
3.1: copper(l) iodide / tetrahydrofuran; diethyl ether / 0.5 h / -50 - -30 °C / Inert atmosphere
3.2: 1.33 h / -78 - 24 °C / Inert atmosphere
With
copper(l) iodide; oxygen; palladium diacetate; pyridinium p-toluenesulfonate;
In
tetrahydrofuran; diethyl ether; dimethyl sulfoxide; acetonitrile;
DOI:10.1021/ja200034b
