(4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate

Base Information

Chemical Name:(4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate
CAS No.:157045-56-2
Molecular Formula:CF₃O₃S*C₁₆H₃₀N₃OPd
Molecular Weight:535.924
Hs Code.:

Synonyms:(4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate

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Chemical Property of (4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate

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Technology Process of (4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate

There total 1 articles about (4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 3030-47-5
N,N,N',N'',N'''-pentamethyldiethylenetriamine

: 696-62-8
para-iodoanisole

: 2923-28-6
silver trifluoromethanesulfonate

: 32005-36-0
bis(dibenzylideneacetone)-palladium⁽⁰⁾

: 157045-56-2
(4-methoxy-1-phenyl)[N,N,N',N'',N''-pentamethyldiethylenetriamine]palladium trifluoromethanesulfonate

Guidance literature:: In acetone; benzene; under N2; to soln. Pd-complex/C6H6 was added the pyridine and the iodo compd., soln. heated (50°C, 1 h), evapn., residue extd. (Et2O, 3 times), residue dissolved in acetone, addn. Ag(CF3SO3), soln. stirred (1h); ppt. filtered off, washed (acetone), evapn. of combined acetone layers (vac.), residue washed (Et2O, 3 times), recrystn. (MeOH/Et2O), elem. anal.;
DOI:10.1021/om00020a043

Reference yield: 79.0%

: 157045-56-2
Pd(CH₃N(C₂H₄N(CH₃)2)2)(C₆H₄OCH₃)⁽¹⁺⁾*CF₃SO₃^(1-)=[Pd(CH₃N(C₂H₄N(CH₃)2)2)(C₆H₄OCH₃)]OSO₂CF₃

: 201230-82-2
carbon monoxide

: 170958-31-3
(4-methoxybenzoylbenzoyl)(N,N,N',N'',N''-pentamethyldiethylenetriamine)palladium trifluoromethanesulfonate

Guidance literature:: In acetone; CO-bubbling (1 min), stirring (1 h); filtering, evapn. (vac.), recrystn. (MeOH / Et2O); elem. anal.;
DOI:10.1021/om00012a032