tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

Base Information

Chemical Name:tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane
CAS No.:214282-73-2
Molecular Formula:C₁₈H₂₈OSi
Molecular Weight:288.505
Hs Code.:

Synonyms:tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

Chemical Property:

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Technology Process of tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

There total 2 articles about tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1444-65-1
(RS)-2-phenylcyclohexanone

: 18162-48-6
tert-butyldimethylsilyl chloride

: 167476-33-7
2-phenyl-1-(tert-butyldimethylsilyloxy)cyclohex-1-ene

: 214282-73-2
tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

Guidance literature:: With triethylamine; In N,N-dimethyl-formamide; at 130 ℃; for 90h; Title compound not separated from byproducts.;
DOI:10.1021/ja001164i

Reference yield:

: 1444-65-1
(RS)-2-phenylcyclohexanone

: 69739-34-0
t-butyldimethylsiyl triflate

: 214282-73-2
tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.8b03733

Reference yield: 45.0%

: 214282-73-2
tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane

: 947-84-2
2-Biphenylcarboxylic acid

: (S)-tert-butyldimethyl((1,4,5,6-tetrahydro-[1,1'-biphenyl]-2-yl)oxy)silane

: tert-butyldimethylsilyl [1,1'-biphenyl]-2-carboxylate

: 1444-65-1,34281-93-1,55700-93-1,34281-94-2
(2S)-2-phenyl-1-cyclohexanone

: 34281-93-1
(R)-2-phenylcyclohexanone

: 167476-33-7
2-phenyl-1-(tert-butyldimethylsilyloxy)cyclohex-1-ene

Guidance literature:: tert-butyldimethyl((1,4,5,6-tetrahydro[1,1'-biphenyl]-2-yl)oxy)silane; With C₁₁₆H₇₃F₁₀N₃O₈P₂S₂; In toluene; at 25 ℃; for 0.0833333h; Resolution of racemate;

2-Biphenylcarboxylic acid; In toluene; at -30 ℃; for 18h; Solvent; Resolution of racemate;
DOI:10.1021/jacs.0c06677