n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide

Base Information

• Chemical Name: n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide
• CAS No.: 78089-45-9
• Molecular Formula: C₂₂H₃₈S
• Molecular Weight: 334.61
• Mol file: 78089-45-9.mol

Synonyms:n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide

Chemical Property of n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide

There total 3 articles about n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-bromo-butane (109-65-9) + 2,4,6-tri-tert-butylbenzenethiol (961-39-7) → n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide (78089-45-9)

Guidance literature:

With sodium hydride; In tetrahydrofuran; 1.) 0 deg C, 2.) 8h, room temp.;

DOI:10.1021/jo00330a017

Reference yield:

1-bromo-2,4,6-tri-tert-butylbenzene (3975-77-7) → n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide (78089-45-9)

Guidance literature:

Multi-step reaction with 3 steps

2: LiAlH₄

3: 90 percent / 1.) NaH / tetrahydrofuran / 1.) 0 deg C, 2.) 8h, room temp.

With lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran;

DOI:10.1021/jo00330a017

Reference yield:

Bis-(2,4,6-tri-tert.-butyl-phenyl)-disulfid (19715-27-6) → n-Butyl 2,4,6-Tri-tert-butylphenyl sulfide (78089-45-9)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄

2: 90 percent / 1.) NaH / tetrahydrofuran / 1.) 0 deg C, 2.) 8h, room temp.

With lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran;

DOI:10.1021/jo00330a017

upstream raw materials:

1-bromo-butane

2,4,6-tri-tert-butylbenzenethiol

1-bromo-2,4,6-tri-tert-butylbenzene

Bis-(2,4,6-tri-tert.-butyl-phenyl)-disulfid

Downstream raw materials:

n-Butyl 2,4,6-tri-tert-butylphenyl sulfoxide