5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)

Base Information

• Chemical Name: 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)
• CAS No.: 101032-21-7
• Molecular Formula: C₁₈H₁₈MnN₂O₄*F₆P
• Molecular Weight: 526.254
• Mol file: 101032-21-7.mol

Synonyms:5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)

Chemical Property of 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)

There total 9 articles about 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

ferrocenium hexafluorophosphate + 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II) (101032-32-0) → ferrocene (102-54-5,55404-68-7) + 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate) (101032-21-7)

Guidance literature:

In acetonitrile; addn. of a soln. of Fe-compound to a suspn. of Mn-complex, stirring for30 min; removing solvent under reduced pressure, removing ferrocene by ether extn., drying in vac. for 2 h;

DOI:10.1016/0304-5102(86)85086-6

Reference yield:

oxo(5,5'-(OCH3)2-salen)manganese(V)PF6 + (phenylthio)acetic acid (103-04-8) → 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate) (101032-21-7) + (phenylsulfinyl)acetic acid (3959-08-8,60833-02-5,60833-03-6,90693-85-9)

Guidance literature:

In acetonitrile; Mn(V) complex reacted with phenylthioacetic acid in CH3CN at 25°C(mechanism discussed); not isolated, detected by UV; Kinetics;

DOI:10.1016/j.molcata.2007.12.004

Reference yield:

oxo(5,5'-(OCH3)2-salen)manganese(V)PF6 + (4-methoxy-phenylsulfanyl)-acetic acid (3406-77-7) → 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate) (101032-21-7) + p-OMeC6H4SOCH2COOH (3996-45-0)

Guidance literature:

In acetonitrile; Mn(V) complex reacted with p-substituted phenylthioacetic acid in CH3CN at 25°C (mechanism discussed); not isolated, detected by UV; Kinetics;

DOI:10.1016/j.molcata.2007.12.004

upstream raw materials:

5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II)

(phenylthio)acetic acid

(4-fluorophenylthio)acetic acid

p-isopropylphenylmercaptoacetic acid