p-OMeC6H4SOCH2COOH

Base Information

• Chemical Name: p-OMeC6H4SOCH2COOH
• CAS No.: 3996-45-0
• Molecular Formula: C₉H₁₀O₄S
• Molecular Weight: 214.242
• Mol file: 3996-45-0.mol

Synonyms:p-OMeC6H4SOCH2COOH

Chemical Property of p-OMeC6H4SOCH2COOH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-OMeC6H4SOCH2COOH

There total 12 articles about p-OMeC6H4SOCH2COOH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(+/-)-Methyl <(4-methoxyphenyl)sulfinyl>acetate (125706-38-9) → (R)-(+)-Methyl <(4-methoxyphenyl)sulfinyl>acetate (125761-97-9) + <(4-Methoxyphenyl)sulfinyl>acetic acid (3996-45-0,125706-43-6) + (S)-(-)-<(4-Methoxyphenyl)sulfinyl>acetic acid (125706-43-6)

Guidance literature:

With water; In toluene; at 25 ℃; for 96h; Yields of byproduct given; Pseudomonas sp. K-10, 0.05M phosphate buffer (pH=7.5);

DOI:10.1016/S0040-4039(01)80467-6

Reference yield:

(4-methoxy-phenylsulfanyl)-acetic acid (3406-77-7) → p-OMeC6H4SOCH2COOH (3996-45-0)

Guidance literature:

With sodium hydrogencarbonate-sodium carbonate buffer (pH: 0.06); chloroamine-T; at 29.9 ℃; Kinetics; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.); var. temperatures;

DOI:10.1246/bcsj.55.289

Reference yield:

4-Methoxybenzenethiol (696-63-9) → p-OMeC6H4SOCH2COOH (3996-45-0)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / 5 h / 120 - 130 °C

2: dihydrogen peroxide

With dihydrogen peroxide; sodium hydroxide;

DOI:10.5012/jkcs.2014.58.1.17

upstream raw materials:

(4-methoxy-phenylsulfanyl)-acetic acid

4-Methoxybenzenethiol

(+/-)-Methyl <(4-methoxyphenyl)sulfinyl>acetate

Downstream raw materials:

p-methoxy-phenylsulphonylacetic acid

p-anisyl methyl sulfone

1-methoxy-4-(methylsulfinyl)benzene

p-Methoxybenzolsulfinyl-p-anisylsulfon