{(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate

Base Information

• Chemical Name: {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate
• CAS No.: 100412-74-6
• Molecular Formula: C₃₅H₂₈N₂PRu*F₆P
• Molecular Weight: 753.629
• Mol file: 100412-74-6.mol

Synonyms:{(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate

Chemical Property of {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate

There total 3 articles about {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

1,10-Phenanthroline (66-71-7) + chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + thallium(I) hexafluorophosphate (60969-19-9) → {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate (100412-74-6)

Guidance literature:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II); thallium(I) hexafluorophosphate; In dichloromethane; at 40 ℃; for 1h; Schlenk technique; Inert atmosphere;

1,10-Phenanthroline; In dichloromethane; at 20 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1039/c6dt01571a

Reference yield: 76.0%

ammonium hexafluorophosphate + chloro(η5-cyclopentadienyl)(1,10-phenanthroline)ruthenium(II) → {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate (100412-74-6)

Guidance literature:

With triphenylphosphine; In ethanol; a suspn. of Ru-complex in EtOH was treated with an ethanol soln. of PPh3 under inert atmosphere, mixt. was heated under reflux for 20 min, filtered, cooled to room temp., a soln. of NH4PF6 in EtOH was added; ppt. was isolated by filtration, washed with Et2O; elem. anal.;

Reference yield:

ammonium hexafluorophosphate + (η5-cyclopentadienyl)(ethanol)(1,10-phenanthroline)ruthenium(II) hexafluorophosphate → {(η5-cyclopentadienyl)(1,10-phenanthroline)(triphenylphosphine)ruthenium} hexafluorophosphate (100412-74-6)

Guidance literature:

With triphenylphosphine; In ethanol; a soln. of Ru-complex in warm ethanol was treated with PPh3 under inert atmosphere, filtered, cooled to room temp., a soln. of NH4PF6 in EtOH was added; ppt. was isolated by filtration, washed with Et2O;

upstream raw materials:

1,10-Phenanthroline

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

thallium(I) hexafluorophosphate