1,2,3-Trichloro-1-propene

Base Information

• Chemical Name: 1,2,3-Trichloro-1-propene
• CAS No.: 96-19-5
• Molecular Formula: C3H3 Cl3
• Molecular Weight: 145.416
• Hs Code.: 2903299090
• DSSTox Substance ID: DTXSID3047766
• Mol file: 96-19-5.mol

Synonyms:1,2,3-trichloro-propene;SCHEMBL185997;DTXSID3047766;FT-0606228;T0396

Chemical Property of 1,2,3-Trichloro-1-propene

Chemical Property:

• Vapor Pressure: 7.14mmHg at 25°C
• Melting Point: -30°C (estimate)
• Refractive Index: 1.5000-1.5020
• Boiling Point: 142°Cat760mmHg
• Flash Point: 65.5°C
• PSA: 0.00000
• Density: 1.376g/cm³
• LogP: 2.54420
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 143.930033
• Heavy Atom Count: 6
• Complexity: 57.1

Purity/Quality:

98% ^*data from raw suppliers

1,2,3-Trichloropropene ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(=CCl)Cl)Cl

Technology Process of 1,2,3-Trichloro-1-propene

There total 19 articles about 1,2,3-Trichloro-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.7%

1,2,2,3-tetrachloropropane (13116-53-5) → 1,2,3-trichloropropene (96-19-5)

Guidance literature:

With triethylbenzylammonium ethanolate; In ethyl acetate;

Reference yield: 38.0%

2,3-dichloro-2-propene-l-ol (2736-73-4,36712-42-2,36712-41-1) → (1Z)-1,2,3-trichloroprop-1-ene (96-19-5,13116-58-0,13116-57-9)

Guidance literature:

With pyridine; sulfuryl dichloride; In dichloromethane; at 0 - 20 ℃; for 2.33333h; Inert atmosphere;

DOI:10.1139/v2012-041

Reference yield: 2.0%

2,3-Dichloroprop-1-ene (78-88-6) → 1,2,3-trichloropropene (96-19-5) + 1,2,2,3-tetrachloropropane (13116-53-5) + 1,1,2,2,3-pentachloropropane (16714-68-4)

Guidance literature:

With chlorine; at 25 ℃; Product distribution; addition of FeCl₃, addition of hydroquinone, periodic or continuous chlorina ion;

upstream raw materials:

1,2,2,3-tetrachloropropane

2-bromo-1,2,3-trichloro-propane

2,3-Dichloroprop-1-ene

1,1,2,3-tetrachloropropane

Downstream raw materials:

2,3-Dichlor-2-propen-1-ol

1,1,2,2,3-pentachloropropane

{[(Z)-4-Chloro-2-methyl-phenylimino]-methyl}-methyl-dithiocarbamic acid (Z)-2,3-dichloro-allyl ester

4-methyl-2-(2,3-dichloro-2-propenyl)phenol