13116-53-5

Basic information

• Product Name: 1,2,2,3-TETRACHLOROPROPANE
• Synonyms: 1,2,2,3-TETRACHLOROPROPANE;1,2,2,3-tetrachloro-propan;TECP;1，2，2，3-terachloro propane;TTCP
• CAS NO: 13116-53-5
• Molecular Formula: C₃H₄Cl₄
• Molecular Weight: 181.88
• EINECS: 236-043-9
• Mol File: 13116-53-5.mol
• Article Data: 13

Chemical Properties

• Melting Point: -50.2°C (estimate)
• Boiling Point: 87-88/50mm
• Flash Point: 62.5°C
• Appearance: /
• Density: 1.50
• Vapor Pressure: 1.48mmHg at 25°C
• Refractive Index: 1.4920 to 1.4950
• CAS DataBase Reference: 1,2,2,3-TETRACHLOROPROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,2,3-TETRACHLOROPROPANE(13116-53-5)
• EPA Substance Registry System: 1,2,2,3-TETRACHLOROPROPANE(13116-53-5)

Safety Data

• RTECS: TZ7000100
• Hazardous Substances Data: 13116-53-5(Hazardous Substances Data)

Usage

General Description

1,2,2,3-Tetrachloropropane is a highly toxic and environmentally hazardous chemical compound. It is primarily used as a solvent and as an intermediate in the manufacturing of other chemicals. Exposure to 1,2,2,3-Tetrachloropropane can occur through inhalation, ingestion, or skin contact, and can lead to adverse health effects including irritation of the respiratory tract, liver and kidney damage, and central nervous system effects. Additionally, 1,2,2,3-Tetrachloropropane is persistent in the environment and can contaminate soil and water, posing a threat to wildlife and human health. Due to its harmful properties, 1,2,2,3-Tetrachloropropane is strictly regulated and efforts are made to reduce its production and use.

InChI:InChI=1/C3H4Cl4/c4-1-3(6,7)2-5/h1-2H2

Upstream product

• 74-99-7 prop-1-yne 
• 78-88-6 2,3-Dichloroprop-1-ene 
• 26198-63-0 1,2-Dichloropropane 
• 96-18-4 1,2,3-trichloropropane 
• 96-19-5 1,2,3-trichloropropene 
• 3175-23-3 1,2,2-trichloropropane 
• 7647-18-9 antimonypentachloride 

Downstream Products

• 16714-68-4 1,1,2,2,3-pentachloropropane 
• 1112-36-3 1,3-dichloro-2,2-difluoropropane 
• 7126-16-1 1,2,3-trichloro-2-fluoro-propane 
• 187737-37-7 propene 
• 74-99-7 prop-1-yne 
• 96-19-5 1,2,3-trichloropropene 
• 24425-97-6 1,1,1,2,2,3-hexachloropropane 
• 15600-01-8 1,1,2,2,3,3-hexachloropropane 
• 13116-58-0 1,2,3-trichloro-1-propene 
• 96-19-5 (1Z)-1,2,3-trichloroprop-1-ene 

Relevant articles and documents

Chlorination of chloroolefins C3-C4

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Method used for preparing chloropropene using microchannel reactors

The invention relates to a method used for preparing chloropropene using microchannel reactors, and more specifically relates to a method used for preparing 1, 1, 2, 2, 3-pentachloropropane or 1, 2, 2, 3-tetrachloropropane via reaction of raw material 1, 2, 3-trichloropropene or 2, 3-dichloropropene with chlorine respectively in Corning microchannel reactors. The method comprises following steps: under light source irradiation (in preparation of 1, 1, 2, 2, 3-pentachloropropane from 2, 3-dichloropropene, light source irradiation is not necessary), chloropropene and chlorine are subjected to preheating to reaction temperature respectively, and then are introduced into a first microchannel reactor for mixing and reaction; an obtained mixture is introduced into a subsequent microchannel reactor or 2 to 4 microchannel reactors connected in series so as to obtain a chloropropene flow. Compared with the prior art, the method comprises following advantages: technology is simple; less three wastes is generated; accurate control of reaction conditions can be realized; yield is high; reaction time is short; and continuous production can be realized.

PROCESS FOR THE PRODUCTION OF CHLORINATED PROPENES

Processes for the production of chlorinated propenes are provided. The processes make use of 1,2-dichloropropane as a starting material and subject a feedstream comprising the same to an ionic chlorination process. At least a portion of any tri- and tetrachlorinated propanes not amenable to ionic chlorination conditions are removed from the ionic chlorination product stream, or, are subjected to chemical base dehydrochlorination step. In this way, recycle of intermediates not amenable to ionic chlorination reactions is reduced or avoided, as is the buildup of these intermediates within the process. Selectivity and, in some embodiments, yield of the process is thus enhanced.

PROCESS FOR THE PRODUCTION OF CHLORINATED PROPANES AND/OR PROPENES

Processes for the production of chlorinated propanes and/or propenes are provided. The present processes make use of methylacetylene, a by-product in the production of ethylene and/or propylene, as a low cost starting material, alone or in combination with propadiene, propene and/or propane. In the latter embodiments, the processes may also be utilized to provide a substantially pure stream of propane.