Carbonic acid isobutyl ester 2-phenyl-allyl ester

Base Information

• Chemical Name: Carbonic acid isobutyl ester 2-phenyl-allyl ester
• CAS No.: 125289-59-0
• Molecular Formula: C₁₄H₁₈O₃
• Molecular Weight: 234.295
• Mol file: 125289-59-0.mol

Synonyms:Carbonic acid isobutyl ester 2-phenyl-allyl ester

Chemical Property of Carbonic acid isobutyl ester 2-phenyl-allyl ester

Chemical Property:

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Technology Process of Carbonic acid isobutyl ester 2-phenyl-allyl ester

There total 1 articles about Carbonic acid isobutyl ester 2-phenyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

3-hydroxy-2-phenylpropene (6006-81-1) + isobutyl chloroformate (543-27-1) → Carbonic acid isobutyl ester 2-phenyl-allyl ester (125289-59-0)

Guidance literature:

With pyridine; In diethyl ether; 1.) 0 deg C, 2 h, 2.) room temperature;

DOI:10.1016/0022-328X(89)87295-X

Reference yield: 68.0%

Carbonic acid isobutyl ester 2-phenyl-allyl ester (125289-59-0) → 3-Phenyl-but-3-enoic acid isobutyl ester (125289-53-4)

Guidance literature:

With palladium diacetate; carbon monoxide; triphenylphosphine; at 50 ℃; under 9120 Torr;

DOI:10.1016/0022-328X(89)87295-X

Reference yield:

Carbonic acid isobutyl ester 2-phenyl-allyl ester (125289-59-0) → 3-Phenyl-butyric acid isobutyl ester

Guidance literature:

Multi-step reaction with 2 steps

1: 68 percent / CO, Pd(OAc)2, PPh₃ / 50 °C / 9120 Torr

2: 95 percent / 6H₁₀)Cl>2 + (R,R)-DIOP, H₂ / benzene / 20 h / 3800 Torr / Ambient temperature

With palladium diacetate; (-)-Diop; carbon monoxide; 2 + (R,R)-DIOP; hydrogen; triphenylphosphine; In benzene;

DOI:10.1016/0022-328X(89)87295-X

upstream raw materials:

3-hydroxy-2-phenylpropene

isobutyl chloroformate

Downstream raw materials:

3-Phenyl-but-3-enoic acid isobutyl ester