ethylenebis(tricyclohexylphosphine)platinum

Base Information

• Chemical Name: ethylenebis(tricyclohexylphosphine)platinum
• CAS No.: 122114-12-9
• Molecular Formula: C₃₈H₇₀P₂Pt
• Molecular Weight: 784.001
• Mol file: 122114-12-9.mol

Synonyms:ethylenebis(tricyclohexylphosphine)platinum

Chemical Property of ethylenebis(tricyclohexylphosphine)platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethylenebis(tricyclohexylphosphine)platinum

There total 5 articles about ethylenebis(tricyclohexylphosphine)platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + tricyclohexylphosphine (2622-14-2) → tetrakis(triphenylphosphine)platinum (14221-02-4) + ethylenebis(tricyclohexylphosphine)platinum (122114-12-9) + tris(triphenylphosphine)platinum(0) (13517-35-6) + {Pt(P(C6H5)3)(P(C6H11)3)(C2H4)} (123894-28-0) + Pt(P(cyclohexyl)3)3 (63175-89-3)

Guidance literature:

In tetrahydrofuran; (argon); NMR tube: addn. of the ligand to the Pt complex in THF at -78°C, slight warming for dissoln., recooling to -80°C; NMR monitoring;

DOI:10.1039/dt9960001039

Reference yield:

ethene (74-85-1) + ((cyclohexyl)3P)2Pt=Si(2,4,6-trimethylphenyl)2 → ethylenebis(tricyclohexylphosphine)platinum (122114-12-9)

Guidance literature:

In benzene-d6; 1 atm ethylene; identified by NMR;

DOI:10.1139/v03-018

Reference yield:

trans-[(Cy3P)2Pt(BF2)Cl] (1352626-70-0) → ethylenebis(tricyclohexylphosphine)platinum (122114-12-9)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene-d6 / 120 h / 20 °C / Schlenk technique; Inert atmosphere; Glovebox

2: benzene / Schlenk technique; Inert atmosphere; Glovebox

In benzene-d6; benzene;

DOI:10.1002/chem.201301056

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

tricyclohexylphosphine

ethene

[(p-CH3-C6H4)3P]2Pt(η(2)-H2C=CH2)

Downstream raw materials:

[Pt(tricyclohexylphosphine)2(η2-PCMe)]

bis(tricyclohexylphosphine)platinum⁽⁰⁾

ethene