[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

Base Information

Chemical Name:[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)
CAS No.:156189-42-3
Molecular Formula:C₇₆H₉₂CuN₄O
Molecular Weight:1141.14
Hs Code.:

Synonyms:[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

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Chemical Property of [2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

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Technology Process of [2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

There total 1 articles about [2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 185447-13-6
[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

: 156189-42-3
[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

Guidance literature:: With sodium hydride; Benzaldoxime; In tetrahydrofuran; dimethyl sulfoxide; mineral oil; NaH/mineral oil/DMSO stirring 30 min (N2), transfer (canula) to benzaldoxime, mixt. transfer (canula) to Cu-compd. soln. (THF), mixt. refluxing in dark for 1 h, cooling (ice bath), diln. (Et2O), org. layer washing (H2O), drying (Na2SO4), filtration; solvent removal, residue chromy. (silica, DCM/light petroleum 1:4);

Reference yield: 76.0%

: 156189-42-3
[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

: 214962-07-9
[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Guidance literature:: With Dess-Martin periodane; In dichloromethane; periodinane addn. to Cu-compd. soln. at room temp. in dark until complete reaction, mixt. filtration after 1.5 h (silica plug), solvent completeremoval; residue chromy. (silica, DCM/light petroleum 2:3); monitoring by TLC (DCM/light petrol 2:3);

Reference yield: 29.0%

: 156189-42-3
[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

: 214962-09-1
[2,2-diacetoxy-3-oxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

Guidance literature:: With lead dioxide; In dichloromethane; acetic acid; Cu-compd. soln. stirring in dark at room temp. for 0.5 h, soln. washing (water, aq. NaHCO3, water), drying (Na2SO4), solvent complete removal; residue chromy. (silica, DCM/light petroleum 2:1);