[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Base Information

• Chemical Name: [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)
• CAS No.: 185447-13-6
• Molecular Formula: C₇₆H₉₁CuN₅O₂
• Molecular Weight: 1170.14
• Mol file: 185447-13-6.mol

Synonyms:[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Chemical Property of [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

There total 1 articles about [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (146164-93-4) + Nitrogen dioxide (10102-44-0) → [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (185447-13-6)

Guidance literature:

In dichloromethane; Petroleum ether; addn. of a soln. of NO2 in light petroleum in small portions to a soln. of copper complex in CH2Cl2; passing through a plug of silica (CH2Cl2), evapn., column chromy (SiO2, CH2Cl2/light petroleum 1:4), evapn.;

DOI:10.1039/b007389j

Reference yield: 92.0%

[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (185447-13-6) → [2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II) (156189-42-3)

Guidance literature:

With sodium hydride; Benzaldoxime; In tetrahydrofuran; dimethyl sulfoxide; mineral oil; NaH/mineral oil/DMSO stirring 30 min (N2), transfer (canula) to benzaldoxime, mixt. transfer (canula) to Cu-compd. soln. (THF), mixt. refluxing in dark for 1 h, cooling (ice bath), diln. (Et2O), org. layer washing (H2O), drying (Na2SO4), filtration; solvent removal, residue chromy. (silica, DCM/light petroleum 1:4);

Reference yield: 89.0%

sodium tetrahydroborate (16940-66-2) + [2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (185447-13-6) → [2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (185447-16-9)

Guidance literature:

With 10percent palladium on activated carbon; In methanol; dichloromethane; addn. of 10% Pd-C to a soln. of copper complex in CH2Cl2-methanol mixt. (4:1), degassing with N2, addn. of NaBH4 in small portions over 6 min, stirring at room temp. in the dark under N2 for 1 h; evapn., passing through a plug of silica (CH2Cl2), evapn., column chromy(SiO2, CH2Cl2/light petroleum 1:4, darkness), evapn., recrystn.(CH2Cl2/ methanol);

DOI:10.1039/b007389j

upstream raw materials:

[5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Nitrogen dioxide

Downstream raw materials:

[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

[2-amino-3-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]copper(II)