[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Base Information

• Chemical Name: [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)
• CAS No.: 214962-07-9
• Molecular Formula: C₇₆H₉₀CuN₄O₂
• Molecular Weight: 1155.12

Synonyms:[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Chemical Property of [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

There total 2 articles about [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II) (156189-42-3) → [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II) (214962-07-9)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; periodinane addn. to Cu-compd. soln. at room temp. in dark until complete reaction, mixt. filtration after 1.5 h (silica plug), solvent completeremoval; residue chromy. (silica, DCM/light petroleum 2:3); monitoring by TLC (DCM/light petrol 2:3);

Reference yield: 37.0%

[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (185447-16-9) → [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II) (214962-07-9)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; addn. of Dess-Martin periodinane to a soln. of copper complex in CH2Cl2,stirring at room temp. in the dark for 5 h, addn. of Dess-Martin period inane, stirring for 11 h; addn. of 1M HCl, stirring for 45 min, washing org. layer with water, 5% NaHCO3, water, drying (Na2SO4), filtration, evapn., column chromy (SiO2,CH2Cl2/light petroleum 2:3-1:1);

DOI:10.1039/b007389j

Reference yield: 88.0%

[Zn(C6H3(C(CH3)3)2C)4(C4H2N)3(C4O2N)] (214962-08-0) + [(C6H3(C(CH3)3)2CC4H2N)3Cu(C6H3(C(CH3)3)2CC4O2N)] (214962-07-9) + (4-bromophenyl)porphyrin-α-dione (1027403-66-2) → 4'-bromophenyl heptakis(3'',5''-di-tert-butylphenyl)bis-porphyrin copper(II)

Guidance literature:

In pyridine; dichloromethane; porphyrin and tetraamine hyrdrochloride were refluxed for 1 h in dry pyridine under argon; copper porphyrin was added, refluxed under argon fro16.5 h, CH2Cl2 added; organic soln. was washed, dried, solvent removed; chromd. (silica, CH2Cl2-petroleum), elem. anal.;

DOI:10.1039/a907059a

upstream raw materials:

[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]copper(II)

Downstream raw materials:

octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 214962-07-9 [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Send

Send

Metric Ton KG G Pound L ML

Send

Send