1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

Base Information

Chemical Name:1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide
CAS No.:74143-73-0
Molecular Formula:C₂₁H₁₇NO₄
Molecular Weight:347.37
Hs Code.:

Synonyms:1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

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Chemical Property of 1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

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Technology Process of 1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

There total 4 articles about 1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 74143-72-9
1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid N-phenyl-2,3-dicarboximide

: 74143-73-0
1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

Guidance literature:: In methanol; diethyl ether; at 0 - 50 ℃;
DOI:10.1021/jo01305a017

Reference yield:

: 95-13-6
1-indene

: 74143-73-0
1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

Guidance literature:: Multi-step reaction with 3 steps

1: 1) 1-butyllithium / 1) hexane, diethyl ether, reflux, 1 h, 2) -78 deg C to room temperature

2: 46 percent / xylene / 9 h / Heating

3: 72 percent / methanol; diethyl ether / 0 - 50 °C

With n-butyllithium; In methanol; diethyl ether; xylene;
DOI:10.1021/jo01305a017

Reference yield:

: 941-69-5
N-phenyl-maleimide

: 74143-73-0
1,2,3,4-tetrahydro-1,4-methanonaphthalene-1,2-endo,3-endo-tricarboxylic acid 1-methyl ester N-phenyl-2,3-dicarboximide

Guidance literature:: Multi-step reaction with 2 steps

1: 46 percent / xylene / 9 h / Heating

2: 72 percent / methanol; diethyl ether / 0 - 50 °C

In methanol; diethyl ether; xylene;
DOI:10.1021/jo01305a017