[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

Base Information

Chemical Name:[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]
CAS No.:532932-53-9
Molecular Formula:C₄₆H₅₉P₂Rh
Molecular Weight:776.827
Hs Code.:

[Rh(triphenylphosphine)(C<sub>5</sub>Me<sub>5</sub>)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

Synonyms:[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

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Chemical Property of [Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

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Technology Process of [Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

There total 1 articles about [Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 532932-52-8
[RhCl₂(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphine)]

: 603-35-0
triphenylphosphine

: 532932-53-9
[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

Guidance literature:: With DBU; In dichloromethane; toluene; byproducts: DBU*HCl; (N2 or Ar); addn. dropwise of soln. of ((t-Bu)3C6H2PH2)(C5Me5)RhCl2 in CH2Cl2 to soln. of DBU (2 equiv.) and PPh3 in toluene; stirring for 5 minat room temp.; removal of solvents, extn. with n-pentane, filtration, concn., cooling at -20°C, crystn., elem. anal.;
DOI:10.1021/om0208624

Reference yield: 99.0%

: 75-09-2
dichloromethane

: 532932-53-9
[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

: dichloro(η5-pentamethylcyclopentadienyl)(triphenylphosphine)rhodium(III)

Guidance literature:: In pentane; byproducts: ((CH3)3C)3C6H2PCH2; (N2 or Ar); treatment of soln. of Rh(PPh3)(C5Me5)(PC6H2(t-Bu)3) in n-pentane with small excess of CH2Cl2 at room temp. for 48 h; pptn., decanting, washing with n-pentane;
DOI:10.1021/om0208624

Reference yield: 99.0%

: 75-11-6
diiodomethane

: 532932-53-9
[Rh(triphenylphosphine)(C₅Me₅)((2,4,6-tri-tert-butylphenyl)phosphinidene)]

: [(η5-pentamethylcyclopentadienyl)RhI2(PPh3)]

Guidance literature:: In pentane; byproducts: ((CH3)3C)3C6H2PCH2; (N2 or Ar); treatment of soln. of Rh(PPh3)(C5Me5)(PC6H2(t-Bu)3) in n-pentane with small excess of CH2I2 at room temp. for 1 h; pptn., decanting, washing with n-pentane;
DOI:10.1021/om0208624