(Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo

Base Information

• Chemical Name: (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo
• CAS No.: 1380093-96-8
• Molecular Formula: C₃₈H₅₅N₆Ni₂O₃S₂*ClO₄
• Molecular Weight: 924.856
• Mol file: 1380093-96-8.mol

Synonyms:(Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo

Chemical Property of (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo

There total 1 articles about (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

lithium perchlorate trihydrate + (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-Cl))(ClO4) (1062114-59-3) + 3-Methoxybenzoic acid (586-38-9) → (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo (1380093-96-8)

Guidance literature:

With triethylamine; In methanol; standard Schlenk techniques under Ar; benzoic-compd. and Et3N in CH3OH added to Ni-compd. in CH3OH, stirred for 2 h at ambient temp., solid Li-compd. added; filtered, washed with CH3OH, dried in vac., recrystallized from CH3CN/EtOH, elem. anal.;

DOI:10.1002/ejic.201200036

Reference yield: 83.0%

lithium perchlorate trihydrate + (Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-3-methoxybenzo (1380093-96-8) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → Ni2(C32H37N6O9S2(CH3)6)(1+)*ClO4(1-)=(Ni2(C32H37N6O9S2(CH3)6))(ClO4) (1380094-00-7)

Guidance literature:

In ethanol; acetonitrile; standard Schlenk techniques under Ar; peroxy-compd. in CH3CN added dropwise at 0°C to Ni-compd. in CH3CN, stirred for 10 min at room temp., solid Li-compd. added, EtOH added; evaporated, filtered, recrystallized from CH3CN/EtOH;

DOI:10.1002/ejic.201200036

upstream raw materials:

(Ni2(3,6,9,17,20,23-hexaazatricyclo[23.3.1.11.15]triaconta-1(28),11,13,15(30),25,26-hexaene-29,30-dithiol(2-)(μ-Cl))(ClO4)

3-Methoxybenzoic acid

Downstream raw materials:

Ni₂(C₃₂H₃₇N₆O₉S₂(CH₃)6)⁽¹⁺⁾*ClO₄^(1-)=(Ni₂(C₃₂H₃₇N₆O₉S₂(CH₃)6))(ClO₄)