{Rh(OC₆H₅)COD}2

Base Information

Chemical Name:{Rh(OC₆H₅)COD}2
CAS No.:60166-13-4
Molecular Formula:C₂₈H₃₄O₂Rh₂
Molecular Weight:608.388
Hs Code.:

Synonyms:{Rh(OC₆H₅)COD}2

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Chemical Property of {Rh(OC₆H₅)COD}2

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Technology Process of {Rh(OC₆H₅)COD}2

There total 2 articles about {Rh(OC₆H₅)COD}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 108-95-2,27073-41-2
phenol

: 60166-13-4
{Rh(OC₆H₅)COD}2

Guidance literature:: With KOH; In dichloromethane; byproducts: KCl, H2O; heatig phenol and KOH (neat) till homogenous soln., addn. to soln. of (RhClCOD)2 (solid precipitated), stirring for 3 h; react. under inert atmosphere; removal of solvent in vacuo, addn. of water and CH2Cl2, stirring vigorously, removal of water layer, washing solid in CH2Cl2-layer with water 4 times, drying in vacuo ; elem. anal.;
DOI:10.1021/om00105a013

Reference yield: 75.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 60166-13-4
{Rh(OC₆H₅)COD}2

Guidance literature:: With potassium; phenol; In tetrahydrofuran; byproducts: KCl; stirring of ((C8H12)RhCl)2 and K in 1:2 molar ratio in phenol/THF at room temp.;; removal of the volatiles under reduced pressure; extn. with CH2Cl2; crystn. in the presence of regulated amts. of CH2Cl2 and phenol; elem. anal.;;

Reference yield: 76.8%

: 60166-13-4
{Rh(OC₆H₅)COD}2

: 34989-06-5
Bis<3-(diphenylphosphino)propyl>phenylphosphin

: 118657-58-2
Rh(OC₆H₅)(ttp)

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

Guidance literature:: In toluene; addn. of soln. of ttp to suspension of Rh-complex, stirring overnight ; all manipulations under inert atmosphere; evapn., addn. of hexane, collection of solid on Schlenck frit, washing with hexane (2 times), toluene and hexane, drying in vacuo, elem. anal.;
DOI:10.1021/om00105a013