(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

Base Information

Chemical Name:(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine
CAS No.:1580458-48-5
Molecular Formula:C₂₈H₂₅N
Molecular Weight:375.513
Hs Code.:

Synonyms:(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

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Technology Process of (S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

There total 4 articles about (S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: C₂₈H₂₃N

: 1580458-48-5
(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

Guidance literature:: With sodium tetrahydroborate; acetic acid; In dichloromethane; at 20 ℃; for 1h; Cooling with ice;
DOI:10.1021/ja501560x

Reference yield:

: 525-03-1
9-aminofluorene

: 1580458-48-5
(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

Guidance literature:: Multi-step reaction with 3 steps

1: dichloromethane; cyclohexane / 2 h / 20 °C / Molecular sieve; Schlenk technique; Inert atmosphere; Cooling with ice

2: (R)-dicycloheptyl(4'-(trimethylsilyl)-[1,1'-binaphthalen]-2-yl)phosphine; bis(η3-allyl-μ-chloropalladium(II)); sodium t-butanolate / cyclohexane / 2 h / 20 °C / Sealed tube; Schlenk technique; Inert atmosphere

3: sodium tetrahydroborate; acetic acid / dichloromethane / 1 h / 20 °C / Cooling with ice

With sodium tetrahydroborate; bis(η3-allyl-μ-chloropalladium(II)); (R)-dicycloheptyl(4'-(trimethylsilyl)-[1,1'-binaphthalen]-2-yl)phosphine; acetic acid; sodium t-butanolate; In dichloromethane; cyclohexane;
DOI:10.1021/ja501560x

Reference yield:

: 1580458-75-8
(E)-N-(3-phenylpropylidene)-9H-fluoren-9-amine

: 1580458-48-5
(S)-N-(1,3-diphenylpropyl)-9H-fluoren-9-amine

Guidance literature:: Multi-step reaction with 2 steps

1: (R)-dicycloheptyl(4'-(trimethylsilyl)-[1,1'-binaphthalen]-2-yl)phosphine; bis(η3-allyl-μ-chloropalladium(II)); sodium t-butanolate / cyclohexane / 2 h / 20 °C / Sealed tube; Schlenk technique; Inert atmosphere

2: sodium tetrahydroborate; acetic acid / dichloromethane / 1 h / 20 °C / Cooling with ice

With sodium tetrahydroborate; bis(η3-allyl-μ-chloropalladium(II)); (R)-dicycloheptyl(4'-(trimethylsilyl)-[1,1'-binaphthalen]-2-yl)phosphine; acetic acid; sodium t-butanolate; In dichloromethane; cyclohexane;
DOI:10.1021/ja501560x