(R,E)-(5-methylhex-3-en-2-yl)benzene

Base Information

Chemical Name:(R,E)-(5-methylhex-3-en-2-yl)benzene
CAS No.:764583-30-4
Molecular Formula:C₁₃H₁₈
Molecular Weight:174.286
Hs Code.:

Synonyms:(R,E)-(5-methylhex-3-en-2-yl)benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R,E)-(5-methylhex-3-en-2-yl)benzene

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of (R,E)-(5-methylhex-3-en-2-yl)benzene

There total 3 articles about (R,E)-(5-methylhex-3-en-2-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 114613-28-4
(3S,4E)-2-methyl-4-hexen-3-yl acetate

: 98-80-6
phenylboronic acid

: 764583-30-4
(R,E)-(5-methylhex-3-en-2-yl)benzene

Guidance literature:: With silver hexafluoroantimonate; 1,10-Phenanthroline; palladium diacetate; In 1,2-dichloro-ethane; at 60 ℃; for 6h; optical yield given as %ee; regiospecific reaction; Inert atmosphere;
DOI:10.1021/ja808673n

Reference yield:

: 78-84-2
isobutyraldehyde

: 98-80-6
phenylboronic acid

: 764583-11-1
2-[(1E)-prop-1-en-1-ylsulfonyl]pyridine

: (3E,2S)-5-methyl-2-phenyl-3-hexene

: (3Z,2S)-5-methyl-2-phenyl-3-hexene

: (3Z,2R)-5-methyl-2-phenyl-3-hexene

: 764583-30-4
(R,E)-(5-methylhex-3-en-2-yl)benzene

Guidance literature:: phenylboronic acid; 2-[(1E)-prop-1-en-1-ylsulfonyl]pyridine; With (2S,3S)-2,3-bis(diphenylphosphino)butane; bis(ethylene)rhodium acetylacetonate; In 1,4-dioxane; water; at 100 ℃; for 12h;

With potassium hexamethylsilazane; In 1,2-dimethoxyethane; toluene; at -78 ℃; for 0.05h;

isobutyraldehyde; In 1,2-dimethoxyethane; toluene; at -78 ℃; for 2h; Further stages. Title compound not separated from byproducts.;
DOI:10.1021/jo7016197

Reference yield:

: 591-50-4
iodobenzene

: (R,Z)-4,4,5,5-tetramethyl-2-(2-methylhex-4-en-3-yl)-1,3,2-dioxaborolane

: C₁₃H₁₈

: 764583-30-4
(R,E)-(5-methylhex-3-en-2-yl)benzene

Guidance literature:: With triphenylphosphine; silver(l) oxide; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1,2-dimethoxyethane; at 90 ℃; for 18h; Overall yield = 77 %; Overall yield = 13.3 mg; enantiospecific reaction; Glovebox;
DOI:10.1002/chem.201303683