HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9

Base Information

Chemical Name:HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9
CAS No.:88610-52-0
Molecular Formula:C₁₂H₄Fe₃O₁₀
Molecular Weight:475.699
Hs Code.:

Synonyms:HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9

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Chemical Property of HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9

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Technology Process of HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9

There total 2 articles about HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112220-73-2
Fe3(μ3-methylidenemethylether)2(carbonyl)9

: 22560-16-3
lithium triethylborohydride

: 17685-52-8
triiron dodecarbonyl

: 103751-58-2
Fe3(μ3-vinylidene)(carbonyl)10

: 112220-75-4
Fe4(μ3-CHCH3)(μ2-carbonyl)(carbonyl)9

: 88610-52-0
HFe(μ3-CCH3)(μ3-carbonyl)(carbonyl)9

: 69440-00-2
(μ-H)3Fe3(μ3-CCH3)(carbonyl)9

Guidance literature:: With CF₃COOH; In tetrahydrofuran; Cooled soln. of Fe complex (-20°C, Ar) is dropwise treated with LiHBEt3 over 5 min, stirring (0.5 h, 1 h without cooling bath), evapn., cooling to -78°C, addn. of CH2Cl2, addn. of CF3COOH, stirring for 15 min, then 15 min at room temp.; Evapn., addn. of n-hexane and H2O, extn. of aq. layer with n-hexane, drying of organic soln. (Na2SO4), chromy. (silica gel, n-hexane, CH2Cl2);

Reference yield:

: 109787-02-2
HN(C₂H₅)3⁽¹⁺⁾*HFe₃(CO)9CCH₂^(1-)=(HN(C₂H₅)3)(HFe₃(CO)9CCH₂)

: 672-66-2
Dimethyl(phenyl)phosphine

: 88610-52-0
HFe₃(CO)9(CO)(CCH₃)

: 109838-63-3
HFe₃(CO)9(P(CH₃)2C₆H₅)(CCH₃)

Guidance literature:: With phosphoric acid; In benzene; PhPMe2 was added to a benzene soln. of Fe3-cluster under inert atmosphere, after 20 min H3PO4 was added, mixt. was stirred for 30 min at 25°C; (1)H NMR showed the presence of both Fe3-products before work-up of the reaction mixt.; solvent was removed, residue was sublimed at 25°C under high vac. (decacarbonyl complex sublimed away leaving phosphine complex), residue was dissolved in a min. of toluene and cooled, crystals were isolated;

Reference yield: 28.0%

: 88610-52-0
(iron)3(carbonyl)10(μ-CCH3)(μ-hydride)

: 501-65-5
diphenyl acetylene

: 110935-15-4
(iron)2(carbonyl)6{HC(phenyl)C(methyl)C(phenyl)C(phenyl)}

: 110935-17-6
(iron)2(carbonyl)6{HC(phenyl)C(phenyl)C(methyl)}

Guidance literature:: In methyl cyclohexane; Under N2, HFe3(CO)10(μ-CCH3) and diphenylacetylene are dissolved in methylcyclohexane, refluxing (1/2 h).; Evapn., column chromy. (Florisil, hexane/toluene with increasing toluene content) gives Fe3(CO)10(μ-CCH2), red band (Fe2(CO)6(HC(Ph)C(Ph)C(Me)), evapn. to red oil, elem. anal.) and orange band. Crystn. (hexane) of orange band, elem. anal..;