(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

Base Information

Chemical Name:(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane
CAS No.:80399-18-4
Molecular Formula:C₂₀H₃₀O₃SSi
Molecular Weight:378.608
Hs Code.:

Synonyms:(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

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Chemical Property of (X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

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Technology Process of (X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

There total 6 articles about (X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 80399-17-3
(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

: 80399-18-4
(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

Guidance literature:: at 650 ℃; under 0.3 Torr;
DOI:10.1021/jo00343a034

Reference yield:

: 29193-71-3
methyl 4-(phenylsulfanyl)butanoate

: 80399-18-4
(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) NCS, 2.) t-BuOK / 1.) CCl₄, reflux, 2.) THF, from -20 deg C to room temp.

2: 86 percent / LiAlH₄ / diethyl ether / Heating

3: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

4: 1.) t-BuOK, 2.) C₅H₅N / 1.) THF, -20 deg C, 2.) ether

5: 100 percent / 650 °C / 0.3 Torr

With pyridine; N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034

Reference yield:

: 63196-76-9,116500-60-8,116500-62-0,144407-72-7
Methyl trans-2-phenylthiocyclopropanecarboxylate

: 80399-18-4
(X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / LiAlH₄ / diethyl ether / Heating

2: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

3: 1.) t-BuOK, 2.) C₅H₅N / 1.) THF, -20 deg C, 2.) ether

4: 100 percent / 650 °C / 0.3 Torr

With pyridine; lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034