Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄)

Base Information

• Chemical Name: Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄)
• CAS No.: 105019-26-9
• Molecular Formula: C₂₈H₂₂FeP₂
• Molecular Weight: 476.277
• Mol file: 105019-26-9.mol

Synonyms:Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄)

Chemical Property of Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄)

There total 1 articles about Fe(C₅H₃(PPh₂)PPh-1,3)(C₅H₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(diphenylphosphin)ferrocene (12098-17-8) + Dichlorophenylphosphine (644-97-3) → (C5H3P(C6H5)2)(PC6H5)Fe(C5H4) (105039-51-8) + Fe(C5H3(PPh2)PPh-1,3)(C5H4) (105019-26-9)

Guidance literature:

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; sodium hydrogencarbonate; In diethyl ether; hexane; Ar-atmosphere; addn. of BuLi (2.1 equivs.) to ferrocene derivative, addn. of TMEDA, stirring (>=20 h), addn. of PhPCl2 (-78°C), stirring(room temp., 1 h); addn. of aq. NaHCO3, extn. (CH2Cl2), solvent removal, chromy. (Al2O3), recrystn. (Et2O/hexane=1:1); elem. anal.;

Reference yield:

Fe(C5H3(PPh2)PPh-1,3)(C5H4) (105019-26-9) + phenyllithium (591-51-5) → 1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8)

Guidance literature:

In diethyl ether; Ar-atmosphere; excess PhLi; mixing at -70°C, warming to room temp.; H2O addn. (cooling), drying of Et2O layer (MgSO4), partial evapn. (vac.), crystn. (hexanes);

upstream raw materials:

(diphenylphosphin)ferrocene

Dichlorophenylphosphine

Downstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

Refernces