[nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4)

Base Information

• Chemical Name: [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4)
• CAS No.: 285116-64-5
• Molecular Formula: C₂₄H₂₀As*C₂₈H₄₀NiS₄
• Molecular Weight: 946.924
• Mol file: 285116-64-5.mol

Synonyms:[nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4)

Chemical Property of [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4)

There total 2 articles about [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C₆H₅)4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-di(t-butyl)benzene-1,2-dithiolate (109082-03-3) → [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C6H5)4) (285116-64-5)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: air / methanol

With air; In methanol;

DOI:10.1016/S0020-1693(99)00608-8

Reference yield:

tetraphenylarsonium chloride monohydrate (104170-16-3) + [nickel(II)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)]Li2 → [nickel(II)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C6H5)4)2 + [nickel(II)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)]N(As(C6H5)4)2*2O(C2H5)2 + [nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C6H5)4) (285116-64-5)

Guidance literature:

In methanol; Ar; dissolved; soln. filtered (ppt. is the (Ni(III)-complex), pptd. (Et2O), crysts. (solvate) separated, washed (MeOH/H2O, Et2O, -90°C), dried (vac., 60°C, 30 h); elem. anal.;

DOI:10.1016/S0020-1693(99)00608-8

Reference yield:

[nickel(III)bis(3,5-ditertiarybutyl-1,2-benzenedithiolate)](As(C6H5)4) (285116-64-5) + carbon monoxide (201230-82-2) → tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

In hydrogenchloride; dichloromethane; 24 h (autoclave, 120 bar, conc. HCl); not isolated, detected by IR;

DOI:10.1016/S0020-1693(99)00608-8

upstream raw materials:

tetraphenylarsonium chloride monohydrate

3,5-di(t-butyl)benzene-1,2-dithiolate

Downstream raw materials:

tetracarbonyl nickel