[PhC(NtBu)₂Ge]₂

Base Information

• Chemical Name: [PhC(NtBu)₂Ge]₂
• CAS No.: 1076188-94-7
• Molecular Formula: C₃₀H₄₆Ge₂N₄
• Molecular Weight: 607.902
• Mol file: 1076188-94-7.mol

Synonyms:[PhC(NtBu)₂Ge]₂

Chemical Property of [PhC(NtBu)₂Ge]₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PhC(NtBu)₂Ge]₂

There total 1 articles about [PhC(NtBu)₂Ge]₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

N,N’-di-tert-butylchloro(phenylamidinate)germanium(II) (1076189-13-3) → [PhC(NtBu)2Ge]2 (1076188-94-7)

Guidance literature:

With potassium; In tetrahydrofuran; under N2 atm. THF was added to mixt. Ge complex and K and stirred for 2 days; solvent was removed in vacuo, residue was extd. with toluene, filtered and concd.; elem. anal.;

DOI:10.1021/om800714f

Reference yield: 61.5%

[PhC(NtBu)2Ge]2 (1076188-94-7) + Azobenzene (1227476-15-4) → [(PhC(N(t-Bu))2)GeN(Ph)]2 (1232394-61-4)

Guidance literature:

In toluene; (N2), Schlenk techniques; stirring mixture of Ge compd. and C6H5NNC6H5 (1:1) in toluene at room temp. overnight; evapn. under reduced pressure, washing with n-hexane, crystn. (toluene) at room temp., isolation of crystals, elem. anal.;

DOI:10.1021/ic100501e

Reference yield: 61.0%

diiron nonacarbonyl (15321-51-4) + [PhC(NtBu)2Ge]2 (1076188-94-7) → [(PhC(N(t-Bu))2)Ge[Fe(carbonyl)4]]2

Guidance literature:

In tetrahydrofuran; (N2), Schlenk techniques; addn. of C4H8O to mixture of Ge compd. and Fe complex (1:2) at ambient temp., stirring for 40 h; evapn. in vacuum, extn. with toluene, filtration, concn., storage at -30°C, isolation of solid, elem. anal.;

DOI:10.1021/ic100501e

upstream raw materials:

N,N’-di-tert-butylchloro(phenylamidinate)germanium(II)

Downstream raw materials:

[(PhC(N(t-Bu))2)GeN(Ph)]2

[(PhC(NtBu)₂)₂Sn:]

N,N’-di-tert-butylchloro(phenylamidinate)germanium(II)

1,1,1,2,2,2-hexamethyldisilane