1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2

Base Information

• Chemical Name: 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2
• CAS No.: 1375172-71-6
• Molecular Formula: C₃₀H₆₀N₆O₂P₄
• Molecular Weight: 660.74
• Mol file: 1375172-71-6.mol

Synonyms:1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2

Chemical Property of 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2

There total 1 articles about 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1,3-di-tert-butyl-2-(tert-butylamino)-4-chloro-1,3,2,4-diazadiphosphetidine (49774-25-6) + recorcinol (108-46-3) → 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2 (1375172-71-6)

Guidance literature:

With triethylamine; In diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/ic300541n

Reference yield: 86.0%

copper(l) iodide (7681-65-4) + 1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2 (1375172-71-6) + acetonitrile (75-05-8,26809-02-9) → [(1,3-C6H4(OP(μ-NtBu)2PN(H)tBu)2)(Cu2(CH3CN)(μ-I)2)2CH3CN](n)

Guidance literature:

In dichloromethane; acetonitrile; (N2, Schlenk) a soln. of CuI in CH3CN was added dropwise to a soln. of cyclodiphosphazane in CH2Cl2, the mixt. was stirred at room temp. for 4 h; ppt. was washed with petroleum ether; elem. anal.;

DOI:10.1021/ic300541n

Reference yield: 85.0%

1,3-C6H4[OP(μ-NtBu)2PN(H)tBu]2 (1375172-71-6) + acetonitrile (75-05-8,26809-02-9) + copper(l) chloride → [(1,3-C6H4(OP(μ-NtBu)2PN(H)tBu)2)(Cu2(CH3CN)(μ-Cl)2)2(CH3CN)](n)*2CH2Cl2

Guidance literature:

In dichloromethane; acetonitrile; (N2, Schlenk) a soln. of CuCl in CH3CN was added dropwise to a soln. of cyclodiphosphazane in CH2Cl2, the mixt. was stirred at room temp. for 4 h; ppt. was washed with petroleum ether; elem. anal.;

DOI:10.1021/ic300541n

upstream raw materials:

1,3-di-tert-butyl-2-(tert-butylamino)-4-chloro-1,3,2,4-diazadiphosphetidine

recorcinol

Downstream raw materials:

[(1,3-C6H4(OP(μ-NtBu)2PN(H)tBu)2)(CuBr)](n)

[(1,3-C6H4(OP(μ-NtBu)2PN(H)tBu)2)(CuI)](n)