10-Dodecen-1-ol, acetate, (10E)-

Base Information

• Chemical Name: 10-Dodecen-1-ol, acetate, (10E)-
• CAS No.: 35153-09-4
• Molecular Formula: C14H26 O2
• Molecular Weight: 226.359
• Hs Code.: 2915390090
• European Community (EC) Number: 252-399-8
• DSSTox Substance ID: DTXSID40865751
• Mol file: 35153-09-4.mol

Synonyms:dodec-10-en-1-yl acetate

Chemical Property of 10-Dodecen-1-ol, acetate, (10E)-

Chemical Property:

• Vapor Pressure: 0.00353mmHg at 25°C
• Boiling Point: 281.6°Cat760mmHg
• Flash Point: 84.1°C
• PSA: 26.30000
• Density: 0.881g/cm³
• LogP: 4.24640
• Storage Temp.: -20°C
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 226.193280068
• Heavy Atom Count: 16
• Complexity: 185

Purity/Quality:

95% ^*data from raw suppliers

Dodec-10-en-1-ylAcetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCCCCCCCCCOC(=O)C
• Uses: Dodec-10-en-1-yl Acetate can be utilized in biological study and synthetic preparation for synthesis and field evaluation of sex pheromone analogs to soybean pod borer Leguminivora glycinivorella for monitoring and pest control use.

Technology Process of 10-Dodecen-1-ol, acetate, (10E)-

There total 15 articles about 10-Dodecen-1-ol, acetate, (10E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-(2-tetrahydropyranyloxy)dodec-10E-ene (87148-46-7) + acetyl chloride (75-36-5) → (E)-10-dodecenyl acetate (35153-09-4)

Guidance literature:

With pyridine; acetic acid;

Reference yield: 68.0%

acetyl chloride (75-36-5) + 1-tert-butoxy-E-10-dodecen (159898-74-5) → (E)-10-dodecenyl acetate (35153-09-4)

Guidance literature:

With acetic acid; at 50 - 55 ℃; for 48h;

Reference yield:

undec-10-yn-1-ol (2774-84-7) → (E)-10-dodecenyl acetate (35153-09-4)

Guidance literature:

Multi-step reaction with 5 steps

1: conc. HCl / 3 h / 20 °C

2: 1.) LiNH₂ / 1.) liq. NH₃, 1 h, 2.) THF, 3 h

3: 16percent H₂SO₄ / ethanol / 1 h / 50 °C

4: 95 percent / LiAlH₄ / bis-(2-methoxy-ethyl) ether / 48 h / 140 °C

5: 7.3 g / pyridine / diethyl ether

With pyridine; hydrogenchloride; lithium aluminium tetrahydride; lithium amide; sulfuric acid; In diethyl ether; ethanol; diethylene glycol dimethyl ether;

DOI:10.1007/BF01373798

upstream raw materials:

1-(2-tetrahydropyranyloxy)dodec-10E-ene

acetyl chloride

1-tert-butoxy-E-10-dodecen

dodec-10-(E)-en-1-ol