[OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄

Base Information

• Chemical Name: [OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄
• CAS No.: 1359766-94-1
• Molecular Formula: C₂₂H₃₃ClO₂OsP*C₂₄H₂₀B
• Molecular Weight: 905.363
• Mol file: 1359766-94-1.mol

Synonyms:[OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄

Chemical Property of [OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄

There total 2 articles about [OsCl(η²-CH₂=CH₂)(η⁶-p-cymene){phenyldiethoxyphosphine}]BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ethene (74-85-1) + [OsCl2(η6-p-cymene){PPh(OEt)2}] (1219623-11-6) + sodium tetraphenyl borate (143-66-8) → [OsCl(η2-CH2=CH2)(η6-p-cymene){phenyldiethoxyphosphine}]BPh4 (1359766-94-1)

Guidance literature:

In ethanol; under inert gas atm., using Schlenk techniques; Os complex, NaBPh4 and EtOH placed in flask, mixt. stirred under ethylene atm. (1 atm) at room temp. for 24 h; solid filtered, crystd. under ethylene from CH2Cl2 and EtOH, elem. anal.;

DOI:10.1016/j.jorganchem.2011.12.032

Reference yield:

ethene (74-85-1) + [OsCl(η6-p-cymene){N2C(H)COOEt}{phenyldiethoxyphosphine}]BPh4 + sodium tetraphenyl borate (143-66-8) → [OsCl(η2-CH2=CH2)(η6-p-cymene){phenyldiethoxyphosphine}]BPh4 (1359766-94-1)

Guidance literature:

ethene; [OsCl(η⁶-p-cymene){N₂C(H)COOEt}{phenyldiethoxyphosphine}]BPh₄; In dichloromethane; for 3h; under 760.051 Torr;

sodium tetraphenyl borate; In ethanol; dichloromethane;

DOI:10.1016/j.poly.2015.11.021

Reference yield: 80.0%

[OsCl(η2-CH2=CH2)(η6-p-cymene){phenyldiethoxyphosphine}]BPh4 (1359766-94-1) + p-toluidine (106-49-0,12221-03-3) → [OsCl(p-tolyl-NH2)(η6-p-cymene)(PPh(OEt)2)](tetraphenylborate) (1247000-47-0)

Guidance literature:

In dichloromethane; to soln. of Os complex added excess of p-toluidine; stirred at room temp. for 2 h; solvent removed under reduced pressure; oil treated with EtOH contg. excess NaBPh4; solid filtered, crystd. from CH2Cl2 and EtOH;

DOI:10.1016/j.jorganchem.2011.12.032

upstream raw materials:

ethene

[OsCl₂(η⁶-p-cymene){PPh(OEt)₂}]

sodium tetraphenyl borate

Downstream raw materials:

[OsCl(p-tolyl-NH2)(η6-p-cymene)(PPh(OEt)2)](tetraphenylborate)

[OsCl(η**(6)-p-cymene)(CH3NHNH2)(PPh(OEt)2](BPh4)