SYNTHESE ET CARACTERISATION PAR RMN 1H D'ALKYL(ARYL)FERRIPORPHYRINES A LIAISON ? METAL-CARBONE

Article abstract of DOI:10.1016/0022-328X(83)80109-0

A series of alkyl(aryl)iron(III) porphyrins with a metal-carbon ? bond has been prepared either by action of an organomagnesium compound on iron(III) chloride porphyrins or by oxidative addition of alkyl halides to iron(I) porphyrins. 1H NMR data have been used to characterize the products obtained.