trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

Base Information

Chemical Name:trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)
CAS No.:123995-84-6
Molecular Formula:C₂₄H₂₂Cl₂N₂OPReS
Molecular Weight:674.604
Hs Code.:

Synonyms:trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

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Chemical Property of trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

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Technology Process of trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

There total 3 articles about trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

: 22325-27-5
4,6-dimethyl-pyrimidine-2-thione

: 123995-84-6
trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

: 62501-45-5
4,6-dimethylpyrimidine-2(1H)-thione hydrochloride

Guidance literature:: With ligroine; In tetrahydrofuran; Addn. of (pymSH) to suspn. of ReOCl3(PPh3)2 (molar ratio 2:1) in THF, refluxing (1 h).; Removal of pptd. C6H9ClN2S, addn. of ligroine to soln., concg., recrystn. from acetone.;
DOI:10.1007/BF01185388

Reference yield:

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

: 22325-27-5
4,6-dimethyl-pyrimidine-2-thione

: 124406-57-1
trans-rhenium(III)(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

: 123995-84-6
trans-rhenium(V)-oxo-(chloro)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

: 62501-45-5
4,6-dimethylpyrimidine-2(1H)-thione hydrochloride

Guidance literature:: In acetone; React. between ReOCl3(PPh3)2 and (pymSH) in boiling acetone with stirring (30 min), color of soln. changing to green on heating, pptg. of yellow cryst. solid (C6H8N2S*HCl).; Removal of pptd. solid through cooling of soln. (room temp.) and filtn., standing of soln. (room temp., 3-4 days), septn. of mixt. of crystals by filtn. of ppt., washing (acetone) and drying (vac.), sepg. of 2 complexes (manually), elem. anal.;
DOI:10.1007/BF01185388