(E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene

Base Information

• Chemical Name: (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene
• CAS No.: 384360-00-3
• Molecular Formula: C₁₉H₁₉NSSi
• Molecular Weight: 321.518
• Mol file: 384360-00-3.mol

Synonyms:(E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene

Chemical Property of (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene

There total 1 articles about (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2-Iodothiophene (3437-95-4,149762-92-5) + iodobenzene (591-50-4) + dimethyl(2-pyridinyl)(vinyl)silane (321155-39-9) → (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene (384360-00-3)

Guidance literature:

iodobenzene; dimethyl(2-pyridinyl)(vinyl)silane; With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; trifuran-2-yl-phosphane; triethylamine; MS₄A; In tetrahydrofuran; at 60 ℃; for 5h;

2-Iodothiophene; In tetrahydrofuran; at 60 ℃; for 42h; Further stages.;

DOI:10.1021/ja016790+

Reference yield: 98.0%

(E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene (384360-00-3) → 2-(1-phenylethenyl)thiophene (30616-74-1)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 60 ℃; for 1h;

DOI:10.1021/ja016790+

Reference yield: 84.0%

m-iodobenzaldehyde (696-41-3) + (E)-1-dimethyl(2-pyridyl)silyl-2-phenyl-2-(2-thienyl)ethene (384360-00-3) → (E)-1-(3-formyl)phenyl-2-phenyl-2-(2-thienyl)ethene

Guidance literature:

With bis(benzonitrile)palladium(II) dichloride; tetrabutyl ammonium fluoride; In tetrahydrofuran; at 60 ℃;

DOI:10.1021/ja016790+

upstream raw materials:

2-Iodothiophene

iodobenzene

dimethyl(2-pyridinyl)(vinyl)silane

Downstream raw materials:

2-(1-phenylethenyl)thiophene