(t-Bu₃SiN=)2(t-Bu₃SiNH)WH

Base Information

Chemical Name:(t-Bu₃SiN=)2(t-Bu₃SiNH)WH
CAS No.:206664-51-9
Molecular Formula:C₃₆H₈₃N₃Si₃W
Molecular Weight:826.182
Hs Code.:

(t-Bu<sub>3</sub>SiN=)2(t-Bu<sub>3</sub>SiNH)WH

Synonyms:(t-Bu₃SiN=)2(t-Bu₃SiNH)WH

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Chemical Property of (t-Bu₃SiN=)2(t-Bu₃SiNH)WH

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Technology Process of (t-Bu₃SiN=)2(t-Bu₃SiNH)WH

There total 2 articles about (t-Bu₃SiN=)2(t-Bu₃SiNH)WH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: Na[W2(μ-Cl)3Cl4(tetrahydrofuran)2]*(tetrahydrofuran)3

: 82135-42-0
tris(tert-butyl)silylamine lithium salt

: 206664-51-9
(t-Bu₃SiN=)2(t-Bu₃SiNH)WH

: 1333-74-0
hydrogen

Guidance literature:: In benzene-d6; byproducts: LiCl, NaCl, THF; a glass bomb reactor with W-complex and Li-compound in benzene was warmed to room temp. and stirred at 23°C for 45 min, volatiles were removed, fresh C6H6 was distilled, 6 h at 100°C (inert atm.); volatiles were removed, the solid was triturated with hexane, filtered, the residue was slurried in THF at -78°C, filtered; elem. anal.;
DOI:10.1021/ja010957h