trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

Base Information

Chemical Name:trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)
CAS No.:464896-33-1
Molecular Formula:C₁₀₈H₁₁₂F₁₀P₄Pt₂
Molecular Weight:2114.12
Hs Code.:

trans,trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P-(CH<sub>2</sub>)18PPh<sub>2</sub>)2-Pt(C<sub>2</sub>)6Pt-(Ph<sub>2</sub>P-(CH<sub>2</sub>)18PPh<sub>2</sub>)(C<sub>6</sub>F<sub>5</sub>)

Synonyms:trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

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Chemical Property of trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

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Technology Process of trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

There total 3 articles about trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: trans,trans-(C₆F₅)((p-tolyl)3P)2Pt(CC)6Pt(P(p-tolyl)3)2(C₆F₅)

: 464896-40-0
(C₆H₅)2P(CH₂)18P(C₆H₅)2

: 464896-33-1
trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

Guidance literature:: In dichloromethane; treated with phosphane in moderate dilute conditions;
DOI:10.1002/1521-3773(20020603)41:11<1871::AID-ANIE1871>3.0.CO;2-V

Reference yield: 20.0%

: 945679-61-8
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)8CH=CH₂)2(C₆F₅)

: 1333-74-0
hydrogen

: 464896-33-1
trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

: 464896-33-1
trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

Guidance literature:: With catalyst: Pd/C; Grubbs catalyst first generation; In ethanol; 1,2-dichloro-ethane; 1. to 5-7% Crubbs'catalyst in CH2Cl2 was added a soln. of complex in CH2Cl2 under refluxing 2 portions over 2 h, chromd. on alumina column (CH2Cl2), evapd.; 2. the crude mixt., 10% Pd/C, ClCH2CH2Cl2, ethanol, 1 atm. of H2, stirred for 7 d; the solvent was rotary evapd., the CH2Cl2-soln. was passed through an alumina column (CH2Cl2), rotary evapd., preparative TLC (silica gel, 60:40v/v hexanes/CH2Cl2);
DOI:10.1021/ja071612n

Reference yield: 20.0%

: 945679-61-8
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)8CH=CH₂)2(C₆F₅)

: 1333-74-0
hydrogen

: 464896-33-1
trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

: 464896-33-1
trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)2-Pt(C₂)6Pt-(Ph₂P-(CH₂)18PPh₂)(C₆F₅)

Guidance literature:: With catalyst: Pd/C; Grubbs catalyst first generation; In ethanol; 1,2-dichloro-ethane; 1. to 5-7% Crubbs'catalyst in CH2Cl2 was added a soln. of complex in CH2Cl2 under refluxing 2 portions over 2 h, chromd. on alumina column (CH2Cl2), evapd.; 2. the crude mixt., 10% Pd/C, ClCH2CH2Cl2, ethanol, 1 atm. of H2, stirred for 7 d; the solvent was rotary evapd., the CH2Cl2-soln. was passed through an alumina column (CH2Cl2), rotary evapd., preparative TLC (silica gel, 60:40v/v hexanes/CH2Cl2);
DOI:10.1021/ja071612n