(+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)

Base Information

Chemical Name:(+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)
CAS No.:88496-14-4
Molecular Formula:C₂₁H₃₄Cl₂P₂Pt
Molecular Weight:614.434
Hs Code.:

Synonyms:(+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)

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Chemical Property of (+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)

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Technology Process of (+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)

There total 1 articles about (+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 82763-84-6
(+/-)-1-(dicyclohexylphosphino)-3-(phenylphosphino)propane

: 88496-14-4
PtCl₂((C₆H₅)2PCH₂CH₂CH₂P(Ph)H)

Guidance literature:: In toluene; benzene; under N2 atm. slurry PtCl2(COD) in benzene treated with toluene soln. cyppH; mixt. filtered, filtrate reduced in stream N2, Et2O added, product filtered; washed with Et2O and recrystd. from CH3NO2; elem. anal.;

Reference yield: 44.0%

: 88496-14-4
(+/-)-dichloro(1-(dicyclohexylphosphino)-3-(phenylphosphino)propane)platinum(II)

: 89173-06-8
trans-dichloro-1,2κ(2)Cl-μ-[[3-(dicyclohexylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(dicyclohexylphosphino-2κP)propyl]phenylphosphido-1:2κP]diplatinum

: (+/-)-cis-dichloro-1,2κ(2)Cl-μ-[[3-(dicyclohexylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(dicyclohexylphosphino-2κP)propyl]phenylphosphido-1:2κP]diplatinum

Guidance literature:: With triethylamine; In tetrahydrofuran; to stirred suspn. of Pt complex in THF added NEt3, stirred for 12 h under N2; filtered, washed (abs. EtOH), dried, dissolved in CH2Cl2, concd. in vac., added Et2O, filtered trans-isomer of product (recrystd. (CH2Cl2/acetone)), filtrate concd., added Et2O, filtered cis-isomer of product (recrystd. (CH2Cl2/acetone)); elem. anal.;
DOI:10.1021/ja00333a036

Reference yield:

: 12005-86-6
sodium hexafluoroarsenate

: 88496-14-4
PtCl₂((C₆H₅)2PCH₂CH₂CH₂P(Ph)H)

: 71734-57-1
1-chloro-3-(dicyclohexylphosphino)propane

: 88496-17-7
(PtCl((C₆H₁₁)2P(CH₂)3P(C₆H₅)(CH₂)3P(C₆H₁₁)2))⁽¹⁺⁾*AsF₆^(1-)=(PtCl((C₆H₁₁)2P(CH₂)3P(C₆H₅)(CH₂)3P(C₆H₁₁)2))AsF₆

Guidance literature:: With triethylamine; In ethanol; toluene; under N2 atm. 1 equiv. (C6H11)2PCH2CH2CH2Cl in toluene added to suspn. PtCl2(cyppH) in ethanol, soln. treated with triethylamine and stirred for 8 h, solvent removed, Et2O added, solid filtered, dissolved in ethanoland refluxed with 1 equiv. NaAsF6; elem. anal.;