(6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)

Base Information

• Chemical Name: (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)
• CAS No.: 80995-57-9
• Molecular Formula: C₃₂H₂₆N₄Ni
• Molecular Weight: 525.275
• Mol file: 80995-57-9.mol

Synonyms:(6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)

Chemical Property of (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)

There total 1 articles about (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

nickel(II) acetate tetrahydrate (6018-89-9) + 1,2-diamino-benzene (95-54-5) + 1-phenylbutan-1,3-dione (93-91-4) → (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza(14)annulenato)nickel(II) (80995-57-9)

Guidance literature:

In methanol; byproducts: H2O; (argon); reflux (8 h); filtration, washing (cold MeOH; Et2O), drying (high vac., 70°C); elem. anal.;

DOI:10.1515/znb-1996-0714

Reference yield: 92.0%

gloutaric dichloride (2873-74-7) + (6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza(14)annulenato)nickel(II) (80995-57-9) → Ni((C5H5O2)2C18H8N4(CH3)2(C6H5)2) (109144-06-1)

Guidance literature:

With triethylamine; In benzene; byproducts: triethylammonium chloride; glutaryl chloride, diluted with benzene was added dropwise to slurry of Ni-complex (molar ratio 4:1) and triethylamine in dry benzene, mixt. heated under gentle reflux for 3.5 h with stirring, left to stand for 24 h; ppt. filtered off, benzene removed on rotary evaporator, residue dissolved in acetone and diluted with cold water, solid filtered off and purified by dissolving in small amt. of dimethylformamide and reprecipitating with cold water; elem. anal.;

DOI:10.1016/S0277-5387(00)81002-5

Reference yield: 39.5%

(6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza(14)annulenato)nickel(II) (80995-57-9) + benzoyl chloride (98-88-4) → [2,3:9,10-dibenzo-6,13-dibenzoyl-7,12-dimethyl-5,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-2,4,6,9,11,13-hexaenato(2-)]nickel(II) + [6-benzoyl-2,3:9,10-dibenzo-7,12-dimethyl-5,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-2,4,6,9,11,13-hexaenato(2-)]nickel(II)

Guidance literature:

With triethylamine; In benzene; byproducts: triethylamine hydrochloride; slurry of Ni complex and Et3N in benzene was treated with soln. of BzCl, refluxed for 1.5 h with stirring (protect from moisture!), allowed to stand at room temp. for 24 h; filtn., drying, treating with hot water while stirring, chromy. on SiO2; recrystallization from aq. EtOH; elem. anal.;

DOI:10.1016/S0277-5387(00)84061-9

upstream raw materials:

nickel(II) acetate tetrahydrate

1,2-diamino-benzene

1-phenylbutan-1,3-dione

Downstream raw materials:

Ni((C₅H₅O₂)2C₁₈H₈N₄(CH₃)2(C₆H₅)2)

Ni((C₆H₄NCCH₃CCC₆H₅N)2HC₅OH₅O)

(6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)-tetra-aza⁽¹⁴⁾annulenato)nickel(II)*CH₂Cl₂