(3R,4S,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Base Information

Chemical Name:(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane
CAS No.:103421-92-7
Molecular Formula:C₁₇H₃₆O₂Si₂
Molecular Weight:328.643
Hs Code.:

Synonyms:(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Suppliers and Price of (3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

There total 6 articles about (3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 103421-92-7
(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

2: p-TsOH-H₂O / acetone / 48 h / Heating

3: LDA, / tetrahydrofuran / 1.) -78 deg C, 1 h; 2.) -78 deg C, 1.5 h then 1 h room temperature

With 2,6-dimethylpyridine; toluene-4-sulfonic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja00278a031

Reference yield:

: 103367-74-4
(7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol

: 103421-92-7
(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

2: p-TsOH-H₂O / acetone / 48 h / Heating

3: LDA, / tetrahydrofuran / 1.) -78 deg C, 1 h; 2.) -78 deg C, 1.5 h then 1 h room temperature

With 2,6-dimethylpyridine; toluene-4-sulfonic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja00278a031

Reference yield:

: 103367-73-3
(7R,9S)-7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-one

: 103421-92-7
(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) L-Selectride; 30 percent hydrogen peroxide / 1.) THF, -78 deg C, 5 h; 2.) -78 - 0 deg C

2: 98 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

3: p-TsOH-H₂O / acetone / 48 h / Heating

4: LDA, / tetrahydrofuran / 1.) -78 deg C, 1 h; 2.) -78 deg C, 1.5 h then 1 h room temperature

With 2,6-dimethylpyridine; dihydrogen peroxide; L-Selectride; toluene-4-sulfonic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja00278a031