cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Base Information

Chemical Name:cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)
CAS No.:107031-78-7
Molecular Formula:C₄₀H₃₆O₂P₂RuS
Molecular Weight:743.808
Hs Code.:

Synonyms:cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

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Chemical Property of cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Chemical Property:

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Technology Process of cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

There total 7 articles about cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 35880-54-7,61647-76-5,184490-77-5,65635-71-4
{ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)}

: 882-33-7
diphenyldisulfane

: 136890-88-5
cis,cis,trans-bis((Ph)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

: 107031-78-7
cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: In benzene-d6; byproducts: PPh3; under Ar, react. in an NMR tube in soln. at room temp.; (31)P NMR detn.;

Reference yield:

: 35880-54-7,61647-76-5,184490-77-5,65635-71-4
{ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)}

: 75-08-1
ethanethiol

: 107031-78-7
cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: In tetrahydrofuran; react. at 20°C; pptn. with hexane;
DOI:10.1016/S0020-1693(00)87726-9

Reference yield:

: 20574-17-8,21029-29-8,239076-83-6
cis,cis,trans-dihydrido(carbonyl)2(triphenylphosphine)2ruthenium(II)

: 75-08-1
ethanethiol

: 107031-78-7
cis,cis,trans-hydrido((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: In tetrahydrofuran; byproducts: H2; excess thiol, 26°C; not isolated, reaction followed by UV/VIS spectroscopy and H2-volumetry; Kinetics;
DOI:10.1016/s0020-1693(96)05251-6