C₁₅H₃₁BO₃Si

Base Information

• Chemical Name: C₁₅H₃₁BO₃Si
• CAS No.: 1092775-33-1
• Molecular Formula: C₁₅H₃₁BO₃Si
• Molecular Weight: 298.306
• Mol file: 1092775-33-1.mol

Synonyms:C₁₅H₃₁BO₃Si

Chemical Property of C₁₅H₃₁BO₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₅H₃₁BO₃Si

There total 1 articles about C₁₅H₃₁BO₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylsilyl chloride (994-30-9) + propargyl alcohol (107-19-7) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → hexaethyl disiloxane (994-49-0) + C15H31BO3Si (1092775-33-1)

Guidance literature:

triethylsilyl chloride; propargyl alcohol; With triethylamine; In dichloromethane; at 0 - 20 ℃; for 3.5h; Inert atmosphere;

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; With zirconocene dichloride; triethylamine; In dichloromethane; for 24h; Reflux; Inert atmosphere;

DOI:10.1021/jacs.1c00462

Reference yield: 84.0%

C15H31BO3Si (1092775-33-1) → (E)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-2-en-1-ol (167896-48-2)

Guidance literature:

With pyridinium p-toluenesulfonate; In methanol; at 20 ℃; for 1h;

Reference yield:

C15H31BO3Si (1092775-33-1) → C17H23BO5

Guidance literature:

Multi-step reaction with 2 steps

1.1: pyridinium p-toluenesulfonate / methanol / 1 h / 20 °C

2.1: triphenylphosphine; carbon tetrabromide / dichloromethane / 0.08 h / 0 °C

2.2: 14 h / 20 °C

With carbon tetrabromide; pyridinium p-toluenesulfonate; triphenylphosphine; In methanol; dichloromethane;

upstream raw materials:

triethylsilyl chloride

propargyl alcohol

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

Downstream raw materials:

(E)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-2-en-1-ol