Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

Base Information

Chemical Name:Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid
CAS No.:142200-26-8
Molecular Formula:C₁₄H₂₅NO₈
Molecular Weight:335.354
Hs Code.:

Synonyms:Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

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Chemical Property of Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

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Technology Process of Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

There total 1 articles about Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 56180-94-0,68107-33-5,106864-09-9
acarbose

: 142200-26-8
Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

Guidance literature:: With acetyl chloride; at 70 ℃; for 14h;
DOI:10.1016/j.tetlet.2016.02.053

Reference yield:

: 142200-26-8
Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

: C₅₃H₆₁NO₁₂

Guidance literature:: Multi-step reaction with 3 steps

1.1: 10-camphorsulfonic acid / N,N-dimethyl-formamide / 2 h / 60 °C

2.1: acetic acid / 1,4-dioxane; water / 6 h / 50 °C

2.2: 2 h / 80 °C

2.3: 14 h

3.1: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C / Inert atmosphere

3.2: 23 h / 20 - 70 °C / Inert atmosphere

With 10-camphorsulfonic acid; sodium hydride; acetic acid; In 1,4-dioxane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2016.02.053

Reference yield:

: 142200-26-8
Methyl-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl>amino-D-glucopyranosid

: C₄₆H₅₇NO₁₂

Guidance literature:: Multi-step reaction with 4 steps

1.1: 10-camphorsulfonic acid / N,N-dimethyl-formamide / 2 h / 60 °C

2.1: acetic acid / 1,4-dioxane; water / 6 h / 50 °C

2.2: 2 h / 80 °C

2.3: 14 h

3.1: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C / Inert atmosphere

3.2: 23 h / 20 - 70 °C / Inert atmosphere

4.1: acetic acid / 1,4-dioxane; water / 20 - 50 °C

With 10-camphorsulfonic acid; sodium hydride; acetic acid; In 1,4-dioxane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2016.02.053