N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

Base Information

Chemical Name:N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide
CAS No.:1402916-94-2
Molecular Formula:C₅₅H₄₅N₃O₄
Molecular Weight:811.98
Hs Code.:

Synonyms:N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

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Chemical Property of N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

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Technology Process of N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

There total 4 articles about N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: N,N′-bis(2′,6′-diisopropylphenyl)-1-amino-perylene-3,4:9,10-tetracarboxylic acid bisimide

: 100-52-7
benzaldehyde

: 1402916-94-2
N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

Guidance literature:: N,N′-bis(2′,6′-diisopropylphenyl)-1-amino-perylene-3,4:9,10-tetracarboxylic acid bisimide; benzaldehyde; With trifluoroacetic acid; In N,N-dimethyl-formamide; at 110 ℃; for 0.5h; Molecular sieve; Schlenk technique; Inert atmosphere;

With oxygen; In N,N-dimethyl-formamide; at 110 ℃; Molecular sieve; Schlenk technique;
DOI:10.1021/acs.joc.6b01573

Reference yield:

: 24544-04-5
2,6-diisopropylbenzenamine

: 1402916-94-2
N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

Guidance literature:: Multi-step reaction with 3 steps

1.1: nitric acid / chloroform / 5 h / 20 °C

1.2: 12 h / 140 °C / Inert atmosphere

2.1: 10% Pd/C; hydrazine / 1,2-dimethoxyethane / 0.25 h / 83 °C

3.1: trifluorormethanesulfonic acid / N,N-dimethyl-formamide / 110 °C

With trifluorormethanesulfonic acid; 10% Pd/C; nitric acid; hydrazine; In 1,2-dimethoxyethane; chloroform; N,N-dimethyl-formamide; 3.1: |Pictet-Spengler Synthesis;
DOI:10.1016/j.tet.2012.08.084

Reference yield:

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

: 1402916-94-2
N,N′-bis(2′,6′-diisopropylphenyl)-13-phenyl-azabenzo[pqr]-perylene-3,4:9,10-tetracarboxylic acid bisimide

Guidance literature:: Multi-step reaction with 3 steps

1.1: nitric acid / chloroform / 5 h / 20 °C

1.2: 12 h / 140 °C / Inert atmosphere

2.1: 10% Pd/C; hydrazine / 1,2-dimethoxyethane / 0.25 h / 83 °C

3.1: trifluorormethanesulfonic acid / N,N-dimethyl-formamide / 110 °C

With trifluorormethanesulfonic acid; 10% Pd/C; nitric acid; hydrazine; In 1,2-dimethoxyethane; chloroform; N,N-dimethyl-formamide; 3.1: |Pictet-Spengler Synthesis;
DOI:10.1016/j.tet.2012.08.084