Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

Base Information

Chemical Name:Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane
CAS No.:779358-31-5
Molecular Formula:C₂₄H₃₂O₃SSi
Molecular Weight:428.668
Hs Code.:

Synonyms:Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

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Technology Process of Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

There total 6 articles about Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 779358-28-0
(1R,4S,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]nonan-8-ol

: 779358-31-5
Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1002/anie.200453859

Reference yield:

: 6090-09-1,57072-59-0,70286-20-3,54973-16-9
methyl-[(1R)-4-methylcyclohex-3-enyl]ketone

: 779358-31-5
Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

2: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

3: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

4: Ph₃P / acetonitrile; CH₂Cl₂ / 0 - 20 °C

5: 95 percent / 2,6-lutidine / CH₂Cl₂

With 2,6-dimethylpyridine; bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1002/anie.200453859

Reference yield:

: 4680-24-4
cis-(R)-limonene oxide

: 779358-31-5
Trimethyl-((1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yloxy)-silane

Guidance literature:: Multi-step reaction with 6 steps

1.1: O₃ / CH₂Cl₂ / -78 °C

1.2: 50 percent / Zn; acetic acid; sodium iodide / sodium acetate

2.1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

3.1: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

4.1: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

5.1: Ph₃P / acetonitrile; CH₂Cl₂ / 0 - 20 °C

6.1: 95 percent / 2,6-lutidine / CH₂Cl₂

With 2,6-dimethylpyridine; bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; ozone; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1002/anie.200453859