9-(tert-butylperoxy)-9H-xanthene

Base Information

• Chemical Name: 9-(tert-butylperoxy)-9H-xanthene
• CAS No.: 71269-25-5
• Molecular Formula: C₁₇H₁₈O₃
• Molecular Weight: 270.328
• Mol file: 71269-25-5.mol

Synonyms:9-(tert-butylperoxy)-9H-xanthene

Chemical Property of 9-(tert-butylperoxy)-9H-xanthene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-(tert-butylperoxy)-9H-xanthene

There total 5 articles about 9-(tert-butylperoxy)-9H-xanthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

9-hydroxyxanthene (90-46-0) → xanthene (92-83-1) + xanth-9-one (90-47-1) + 9-(tert-butylperoxy)-9H-xanthene (71269-25-5) + dixanthyl ether (6538-19-8)

Guidance literature:

With 2-Picolinic acid; tert.-butylhydroperoxide; In pyridine; acetic acid; at 20 ℃; for 1h; Title compound not separated from byproducts;

DOI:10.1016/S0040-4020(01)80814-0

Reference yield: 66.0%

9-hydroxyxanthene (90-46-0) + tert.-butylhydroperoxide (75-91-2) → xanthene (92-83-1) + xanth-9-one (90-47-1) + 9-(tert-butylperoxy)-9H-xanthene (71269-25-5) + dixanthyl ether (6538-19-8)

Guidance literature:

With 2-Picolinic acid; In pyridine; acetic acid; at 20 ℃; for 1h; Title compound not separated from byproducts;

DOI:10.1016/S0040-4020(01)80814-0

Reference yield:

xanthene (92-83-1) → 9-hydroxyxanthene (90-46-0) + xanth-9-one (90-47-1) + 9-(tert-butylperoxy)-9H-xanthene (71269-25-5)

Guidance literature:

With tert.-butylhydroperoxide; ferric nitrate; In pyridine; for 1h; Product distribution; Ambient temperature; effect of O₂;

DOI:10.1016/S0040-4020(98)00974-0

upstream raw materials:

9-hydroxyxanthene

tert.-butylhydroperoxide

xanthene

Downstream raw materials:

xanth-9-one

(±)-9-(1'-oxo-2'-cyclopentyl)xanthene

Refernces

• 1、 Barton, Derek H. R.,Le Gloahec, Valerie N.. "The radical chemistry of t-butyl hydroperoxide (TBHP) - Part 3 - Further studies on hydrocarbon activation". . p. 15457 - 15468. Retrieved 2007/10/03.