[2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane

Base Information

• Chemical Name: [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane
• CAS No.: 727726-30-9
• Molecular Formula: C₂₃H₂₃FS₂Si
• Molecular Weight: 410.652
• Mol file: 727726-30-9.mol

Synonyms:[2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane

Chemical Property of [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane

There total 1 articles about [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

difluorodiphenylsilane (312-40-3) + 2-benzyl-1,3-dithiane (31593-52-9) → [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane (727726-30-9)

Guidance literature:

2-benzyl-1,3-dithiane; With n-butyllithium; at -78 ℃;

difluorodiphenylsilane; at 20 ℃;

DOI:10.1016/j.bmcl.2004.03.042

Reference yield: 65.0%

1-[((S)-3-iodo-2-methylpropoxy)methyl]benzene (72297-80-4) + [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane (727726-30-9) → [(2S)-2-methyl-3-(phenylmethoxy)-1-propyl][2-(phenylmethyl)-1,3-dithian-2-yl]diphenylsilane (727726-29-6)

Guidance literature:

1-[((S)-3-iodo-2-methylpropoxy)methyl]benzene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 - 20 ℃; for 0.833333h;

[2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane; In diethyl ether; pentane; at -78 - 20 ℃;

DOI:10.1021/jo048121v

Reference yield: 65.0%

(2R)-3-iodo-2-methylpropyl benzyl ether (90344-49-3) + [2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane (727726-30-9) → [(2R)-2-methyl-3-(phenylmethoxy)-1-propyl][2-(phenylmethyl)-1,3-dithian-2-yl]diphenylsilane (727726-31-0)

Guidance literature:

(2R)-3-iodo-2-methylpropyl benzyl ether; With tert.-butyl lithium; In diethyl ether; pentane; at -78 - 20 ℃; for 0.833333h;

[2-(phenylmethyl)-1,3-dithian-2-yl]fluorodiphenylsilane; In diethyl ether; pentane; at -78 - 20 ℃;

DOI:10.1021/jo048121v

upstream raw materials:

difluorodiphenylsilane

2-benzyl-1,3-dithiane

Downstream raw materials:

[(2S)-2-methyl-3-(phenylmethoxy)-1-propyl][2-(phenylmethyl)-1,3-dithian-2-yl]diphenylsilane

[(2R)-2-methyl-3-(phenylmethoxy)-1-propyl][2-(phenylmethyl)-1,3-dithian-2-yl]diphenylsilane

[(2R)-2-methyl-3-(phenylmethoxy)-1-propyl][1-amino-2-phenylethyl]diphenylsilane

[(2R)-2-methyl-3-(phenylmethoxy)-1-propyl][2-phenyl-1-hydroxyethyl]diphenylsilane